A novel hybrid carbon material

A.G. Nasibulin, P.V. Pikhitsa, Hua Jiang, D.P. Brown, A.V. Krasheninnikov, A.S. Anis, P. Queipo, A. Moisala, D. Gonzalez, G. Lientschnig, A. Hassanien, S.D. Shandakov, G. Lolli, D.E. Resasco, M. Choi, D. Tomanek, Esko I. Kauppinen

Research output: Contribution to journalArticleScientificpeer-review

275 Citations (Scopus)

Abstract

Both fullerenes and single-walled carbon nanotubes (SWNTs) exhibit many advantageous properties. Despite the similarities between these two forms of carbon, there have been very few attempts to physically merge them. We have discovered a novel hybrid material that combines fullerenes and SWNTs into a single structure in which the fullerenes are covalently bonded to the outer surface of the SWNTs. These fullerene-functionalized SWNTs, which we have termed NanoBuds, were selectively synthesized in two different one-step continuous methods, during which fullerenes were formed on iron-catalyst particles together with SWNTs during CO disproportionation. The field-emission characteristics of NanoBuds suggest that they may possess advantageous properties compared with single-walled nanotubes or fullerenes alone, or in their non-bonded configurations.
Original languageEnglish
Pages (from-to)156-161
JournalNature Nanotechnology
Volume2
Issue number3
DOIs
Publication statusPublished - 2007
MoE publication typeA1 Journal article-refereed

Fingerprint

Fullerenes
fullerenes
Single-walled carbon nanotubes (SWCN)
Carbon
carbon nanotubes
carbon
Hybrid materials
Carbon Monoxide
Field emission
Nanotubes
field emission
nanotubes
Iron
iron
catalysts
Catalysts
configurations

Keywords

  • carbon nanotubes
  • fullerenes
  • SWNT

Cite this

Nasibulin, A. G., Pikhitsa, P. V., Jiang, H., Brown, D. P., Krasheninnikov, A. V., Anis, A. S., ... Kauppinen, E. I. (2007). A novel hybrid carbon material. Nature Nanotechnology, 2(3), 156-161. https://doi.org/10.1038/nnano.2007.37
Nasibulin, A.G. ; Pikhitsa, P.V. ; Jiang, Hua ; Brown, D.P. ; Krasheninnikov, A.V. ; Anis, A.S. ; Queipo, P. ; Moisala, A. ; Gonzalez, D. ; Lientschnig, G. ; Hassanien, A. ; Shandakov, S.D. ; Lolli, G. ; Resasco, D.E. ; Choi, M. ; Tomanek, D. ; Kauppinen, Esko I. / A novel hybrid carbon material. In: Nature Nanotechnology. 2007 ; Vol. 2, No. 3. pp. 156-161.
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Nasibulin, AG, Pikhitsa, PV, Jiang, H, Brown, DP, Krasheninnikov, AV, Anis, AS, Queipo, P, Moisala, A, Gonzalez, D, Lientschnig, G, Hassanien, A, Shandakov, SD, Lolli, G, Resasco, DE, Choi, M, Tomanek, D & Kauppinen, EI 2007, 'A novel hybrid carbon material', Nature Nanotechnology, vol. 2, no. 3, pp. 156-161. https://doi.org/10.1038/nnano.2007.37

A novel hybrid carbon material. / Nasibulin, A.G.; Pikhitsa, P.V.; Jiang, Hua; Brown, D.P.; Krasheninnikov, A.V.; Anis, A.S.; Queipo, P.; Moisala, A.; Gonzalez, D.; Lientschnig, G.; Hassanien, A.; Shandakov, S.D.; Lolli, G.; Resasco, D.E.; Choi, M.; Tomanek, D.; Kauppinen, Esko I.

In: Nature Nanotechnology, Vol. 2, No. 3, 2007, p. 156-161.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - A novel hybrid carbon material

AU - Nasibulin, A.G.

AU - Pikhitsa, P.V.

AU - Jiang, Hua

AU - Brown, D.P.

AU - Krasheninnikov, A.V.

AU - Anis, A.S.

AU - Queipo, P.

AU - Moisala, A.

AU - Gonzalez, D.

AU - Lientschnig, G.

AU - Hassanien, A.

AU - Shandakov, S.D.

AU - Lolli, G.

AU - Resasco, D.E.

AU - Choi, M.

AU - Tomanek, D.

AU - Kauppinen, Esko I.

PY - 2007

Y1 - 2007

N2 - Both fullerenes and single-walled carbon nanotubes (SWNTs) exhibit many advantageous properties. Despite the similarities between these two forms of carbon, there have been very few attempts to physically merge them. We have discovered a novel hybrid material that combines fullerenes and SWNTs into a single structure in which the fullerenes are covalently bonded to the outer surface of the SWNTs. These fullerene-functionalized SWNTs, which we have termed NanoBuds, were selectively synthesized in two different one-step continuous methods, during which fullerenes were formed on iron-catalyst particles together with SWNTs during CO disproportionation. The field-emission characteristics of NanoBuds suggest that they may possess advantageous properties compared with single-walled nanotubes or fullerenes alone, or in their non-bonded configurations.

AB - Both fullerenes and single-walled carbon nanotubes (SWNTs) exhibit many advantageous properties. Despite the similarities between these two forms of carbon, there have been very few attempts to physically merge them. We have discovered a novel hybrid material that combines fullerenes and SWNTs into a single structure in which the fullerenes are covalently bonded to the outer surface of the SWNTs. These fullerene-functionalized SWNTs, which we have termed NanoBuds, were selectively synthesized in two different one-step continuous methods, during which fullerenes were formed on iron-catalyst particles together with SWNTs during CO disproportionation. The field-emission characteristics of NanoBuds suggest that they may possess advantageous properties compared with single-walled nanotubes or fullerenes alone, or in their non-bonded configurations.

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JO - Nature Nanotechnology

JF - Nature Nanotechnology

SN - 1748-3387

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Nasibulin AG, Pikhitsa PV, Jiang H, Brown DP, Krasheninnikov AV, Anis AS et al. A novel hybrid carbon material. Nature Nanotechnology. 2007;2(3):156-161. https://doi.org/10.1038/nnano.2007.37