Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts

Tiia Viinikainen (Corresponding Author), Hanne Rönkkönen, Heather Bradshaw, Hazel Stephenson, Sanna Airaksinen, Matti Reinikainen, Pekka Simell, Outi Krause

Research output: Contribution to journalArticleScientificpeer-review

51 Citations (Scopus)

Abstract

The surface structures of ZrO2, Y2O3–ZrO2 and SiO2–ZrO2 catalysts were studied in relation to their basicity and acidity, and the relationship between surface structure and gasification gas clean-up activity was evaluated. The physical properties of the catalysts were characterized by BET, XRD and Raman spectroscopy. The basicity and acidity of the catalysts were measured by CO2-TPD and NH3-TPD, respectively. The types of active surface sites were determined by in situ DRIFTS experiments for the adsorption and desorption of CO2. The order of activity of the catalysts in the decomposition of tar from synthetic gasification gas was ZrO2 > Y2O3–ZrO2 > SiO2–ZrO2. Acidity was observed to be an unfavorable characteristic for ZrO2-based gas clean-up catalysts, whereas basicity seems to be essential. The redox properties of Y2O3–ZrO2 enhance its overall oxidation activity and the lower performance of Y2O3–ZrO2 in tar decomposition compared to ZrO2 can be explained by its oxidation activity towards other gas compounds than tar.
Original languageEnglish
Pages (from-to)169-177
Number of pages9
JournalApplied Catalysis A: General
Volume362
Issue number1-2
DOIs
Publication statusPublished - 2009
MoE publication typeA1 Journal article-refereed

Fingerprint

Gasification
Zirconia
Biomass
Tars
Gases
Tar
Alkalinity
Catalysts
Acidity
Temperature programmed desorption
Surface structure
Thermodynamic properties
Decomposition
Oxidation
Raman spectroscopy
Desorption
Physical properties
zirconium oxide
Adsorption
Experiments

Keywords

  • Zirconia
  • Gasification gas clean-up
  • Characterization of surface sites

Cite this

Viinikainen, T., Rönkkönen, H., Bradshaw, H., Stephenson, H., Airaksinen, S., Reinikainen, M., ... Krause, O. (2009). Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts. Applied Catalysis A: General, 362(1-2), 169-177. https://doi.org/10.1016/j.apcata.2009.04.037
Viinikainen, Tiia ; Rönkkönen, Hanne ; Bradshaw, Heather ; Stephenson, Hazel ; Airaksinen, Sanna ; Reinikainen, Matti ; Simell, Pekka ; Krause, Outi. / Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts. In: Applied Catalysis A: General. 2009 ; Vol. 362, No. 1-2. pp. 169-177.
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abstract = "The surface structures of ZrO2, Y2O3–ZrO2 and SiO2–ZrO2 catalysts were studied in relation to their basicity and acidity, and the relationship between surface structure and gasification gas clean-up activity was evaluated. The physical properties of the catalysts were characterized by BET, XRD and Raman spectroscopy. The basicity and acidity of the catalysts were measured by CO2-TPD and NH3-TPD, respectively. The types of active surface sites were determined by in situ DRIFTS experiments for the adsorption and desorption of CO2. The order of activity of the catalysts in the decomposition of tar from synthetic gasification gas was ZrO2 > Y2O3–ZrO2 > SiO2–ZrO2. Acidity was observed to be an unfavorable characteristic for ZrO2-based gas clean-up catalysts, whereas basicity seems to be essential. The redox properties of Y2O3–ZrO2 enhance its overall oxidation activity and the lower performance of Y2O3–ZrO2 in tar decomposition compared to ZrO2 can be explained by its oxidation activity towards other gas compounds than tar.",
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Viinikainen, T, Rönkkönen, H, Bradshaw, H, Stephenson, H, Airaksinen, S, Reinikainen, M, Simell, P & Krause, O 2009, 'Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts', Applied Catalysis A: General, vol. 362, no. 1-2, pp. 169-177. https://doi.org/10.1016/j.apcata.2009.04.037

Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts. / Viinikainen, Tiia (Corresponding Author); Rönkkönen, Hanne; Bradshaw, Heather; Stephenson, Hazel; Airaksinen, Sanna; Reinikainen, Matti; Simell, Pekka; Krause, Outi.

In: Applied Catalysis A: General, Vol. 362, No. 1-2, 2009, p. 169-177.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Acidic and basic surface sites of zirconia-based biomass gasification gas clean-up catalysts

AU - Viinikainen, Tiia

AU - Rönkkönen, Hanne

AU - Bradshaw, Heather

AU - Stephenson, Hazel

AU - Airaksinen, Sanna

AU - Reinikainen, Matti

AU - Simell, Pekka

AU - Krause, Outi

PY - 2009

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N2 - The surface structures of ZrO2, Y2O3–ZrO2 and SiO2–ZrO2 catalysts were studied in relation to their basicity and acidity, and the relationship between surface structure and gasification gas clean-up activity was evaluated. The physical properties of the catalysts were characterized by BET, XRD and Raman spectroscopy. The basicity and acidity of the catalysts were measured by CO2-TPD and NH3-TPD, respectively. The types of active surface sites were determined by in situ DRIFTS experiments for the adsorption and desorption of CO2. The order of activity of the catalysts in the decomposition of tar from synthetic gasification gas was ZrO2 > Y2O3–ZrO2 > SiO2–ZrO2. Acidity was observed to be an unfavorable characteristic for ZrO2-based gas clean-up catalysts, whereas basicity seems to be essential. The redox properties of Y2O3–ZrO2 enhance its overall oxidation activity and the lower performance of Y2O3–ZrO2 in tar decomposition compared to ZrO2 can be explained by its oxidation activity towards other gas compounds than tar.

AB - The surface structures of ZrO2, Y2O3–ZrO2 and SiO2–ZrO2 catalysts were studied in relation to their basicity and acidity, and the relationship between surface structure and gasification gas clean-up activity was evaluated. The physical properties of the catalysts were characterized by BET, XRD and Raman spectroscopy. The basicity and acidity of the catalysts were measured by CO2-TPD and NH3-TPD, respectively. The types of active surface sites were determined by in situ DRIFTS experiments for the adsorption and desorption of CO2. The order of activity of the catalysts in the decomposition of tar from synthetic gasification gas was ZrO2 > Y2O3–ZrO2 > SiO2–ZrO2. Acidity was observed to be an unfavorable characteristic for ZrO2-based gas clean-up catalysts, whereas basicity seems to be essential. The redox properties of Y2O3–ZrO2 enhance its overall oxidation activity and the lower performance of Y2O3–ZrO2 in tar decomposition compared to ZrO2 can be explained by its oxidation activity towards other gas compounds than tar.

KW - Zirconia

KW - Gasification gas clean-up

KW - Characterization of surface sites

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DO - 10.1016/j.apcata.2009.04.037

M3 - Article

VL - 362

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JO - Applied Catalysis A: General

JF - Applied Catalysis A: General

SN - 0926-860X

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ER -