Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity

Anna-Stiina Jääskeläinen, Tiina Liitiä, Atte Mikkelson, Tarja Tamminen

Research output: Contribution to journalArticleScientificpeer-review

39 Citations (Scopus)
28 Downloads (Pure)

Abstract

Lignin's heterogeneous polymeric structure limits its utilisation in high-value applications. This paper describes a protocol for kraft lignin precipitation fractionation from aqueous ethanol, acetone and propyleneglycol monomethyl ether solution by adding water as nonsolvent. The solvent-insoluble fractions possessed high molar mass (Mw 4300-18900 g/mol), high polydispersity (2.2-5.6), high nitrogen (0.15-0.43%) and low sulphur (0.7-1.5%) content. Even lignin aggregation was observed in acetone-based process. The molar mass of the precipitated fractions depended on the amount of water added in the precipitation step. The highly soluble lignin fractions possessed very low molar mass (Mw 1100-1200 g/mol), more free phenolic hydroxyl groups (3.95-4.05 mmol/g), carboxylic acid groups (0.56-0.71 mmol/g), higher amount of sulphur (1.6k2.9%) and more carbohydrates (5.3-6.1%) than other lignin fractions. The presented protocol provides a selection of green solvents for a simple and easily scalable and tunable lignin fractionation process to produce lignin with constant quality and high purity.
Original languageEnglish
Pages (from-to)51-58
Number of pages8
JournalIndustrial Crops and Products
Volume103
DOIs
Publication statusPublished - 2017
MoE publication typeNot Eligible

Fingerprint

purity
lignin
fractionation
water
molecular weight
acetone
sulfur
carboxylic acids
ethers
ethanol
carbohydrates
nitrogen

Keywords

  • acetone
  • ethanol
  • fractionation
  • kraft lignin
  • molar mass
  • propyleneglycol monomethyl ether

Cite this

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title = "Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity",
abstract = "Lignin's heterogeneous polymeric structure limits its utilisation in high-value applications. This paper describes a protocol for kraft lignin precipitation fractionation from aqueous ethanol, acetone and propyleneglycol monomethyl ether solution by adding water as nonsolvent. The solvent-insoluble fractions possessed high molar mass (Mw 4300-18900 g/mol), high polydispersity (2.2-5.6), high nitrogen (0.15-0.43{\%}) and low sulphur (0.7-1.5{\%}) content. Even lignin aggregation was observed in acetone-based process. The molar mass of the precipitated fractions depended on the amount of water added in the precipitation step. The highly soluble lignin fractions possessed very low molar mass (Mw 1100-1200 g/mol), more free phenolic hydroxyl groups (3.95-4.05 mmol/g), carboxylic acid groups (0.56-0.71 mmol/g), higher amount of sulphur (1.6k2.9{\%}) and more carbohydrates (5.3-6.1{\%}) than other lignin fractions. The presented protocol provides a selection of green solvents for a simple and easily scalable and tunable lignin fractionation process to produce lignin with constant quality and high purity.",
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Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity. / Jääskeläinen, Anna-Stiina; Liitiä, Tiina; Mikkelson, Atte; Tamminen, Tarja.

In: Industrial Crops and Products, Vol. 103, 2017, p. 51-58.

Research output: Contribution to journalArticleScientificpeer-review

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T1 - Aqueous organic solvent fractionation as means to improve lignin homogeneity and purity

AU - Jääskeläinen, Anna-Stiina

AU - Liitiä, Tiina

AU - Mikkelson, Atte

AU - Tamminen, Tarja

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