Atomic and molecular layer deposition for surface modification

Mika Vähä-Nissi, Jenni Sievänen, Erkki Salo, Pirjo Heikkilä, L.-S. Johansson, Jorma Koskinen, Ali Harlin

Research output: Contribution to conferenceConference AbstractScientificpeer-review

Abstract

Atomic and molecular layer deposition (ALD and MLD, respectively) techniques are examples of self-assembly based on repeated cycles of self-limiting gas-solid reactions. The precursors are pulsed into a reactor alternately, separated by inert gas pulses. During a single cycle, only one molecular layer is deposited on the surface, enabling tailored film composition in principle down to molecular resolution on ideal surfaces. These cycles are repeated until a layer with a specific thickness is achieved. Few materials are, however, ideal. During the early film growth precursors adsorb onto the surface and absorb into the near-surface regions depending both on the substrate and the deposition parameters. These precursors can react with the substrate affecting e.g. mechanical, barrier and surface properties. The deposited material starts then to form clusters leading to nonuniform early film growth. The purpose of this presentation is to demonstrate that thin and non-uniform layers can be used to tailor the surface characteristics of different substrates. For example, print quality (ink spreading and penetration) of inkjet printing on polymer films can be adjusted with metal oxide. Secondly, this can be used to control water penetration into porous nonwovens. Third example demonstrates how adhesion of extrusion coated biopolymer to inorganic oxides can be improved with a novel hybrid layer based on lactic acid. As the amount of material to be deposited is small, this will help to increase the speed in ALD/MLD processes designed for moving webs.
Original languageEnglish
Publication statusPublished - 2013
Event7th International Conference on Materials for Advanced Technologies, ICMAT 2013 - Singapore, Hong Kong
Duration: 30 Jun 20135 Jul 2013

Conference

Conference7th International Conference on Materials for Advanced Technologies, ICMAT 2013
Abbreviated titleICMAT 2013
CountryHong Kong
CitySingapore
Period30/06/135/07/13

Fingerprint

cycles
penetration
lactic acid
biopolymers
inks
printing
surface properties
metal oxides
self assembly
rare gases
adhesion
reactors
mechanical properties
oxides
polymers
pulses
gases
water

Keywords

  • adhesion
  • ALd
  • atomic layer deposition
  • hybrid
  • inorganic
  • surface treatment

Cite this

Vähä-Nissi, M., Sievänen, J., Salo, E., Heikkilä, P., Johansson, L-S., Koskinen, J., & Harlin, A. (2013). Atomic and molecular layer deposition for surface modification. Abstract from 7th International Conference on Materials for Advanced Technologies, ICMAT 2013, Singapore, Hong Kong.
Vähä-Nissi, Mika ; Sievänen, Jenni ; Salo, Erkki ; Heikkilä, Pirjo ; Johansson, L.-S. ; Koskinen, Jorma ; Harlin, Ali. / Atomic and molecular layer deposition for surface modification. Abstract from 7th International Conference on Materials for Advanced Technologies, ICMAT 2013, Singapore, Hong Kong.
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Vähä-Nissi, M, Sievänen, J, Salo, E, Heikkilä, P, Johansson, L-S, Koskinen, J & Harlin, A 2013, 'Atomic and molecular layer deposition for surface modification', 7th International Conference on Materials for Advanced Technologies, ICMAT 2013, Singapore, Hong Kong, 30/06/13 - 5/07/13.

Atomic and molecular layer deposition for surface modification. / Vähä-Nissi, Mika; Sievänen, Jenni; Salo, Erkki; Heikkilä, Pirjo; Johansson, L.-S.; Koskinen, Jorma; Harlin, Ali.

2013. Abstract from 7th International Conference on Materials for Advanced Technologies, ICMAT 2013, Singapore, Hong Kong.

Research output: Contribution to conferenceConference AbstractScientificpeer-review

TY - CONF

T1 - Atomic and molecular layer deposition for surface modification

AU - Vähä-Nissi, Mika

AU - Sievänen, Jenni

AU - Salo, Erkki

AU - Heikkilä, Pirjo

AU - Johansson, L.-S.

AU - Koskinen, Jorma

AU - Harlin, Ali

N1 - Project code: 78677 Project code: 78230

PY - 2013

Y1 - 2013

N2 - Atomic and molecular layer deposition (ALD and MLD, respectively) techniques are examples of self-assembly based on repeated cycles of self-limiting gas-solid reactions. The precursors are pulsed into a reactor alternately, separated by inert gas pulses. During a single cycle, only one molecular layer is deposited on the surface, enabling tailored film composition in principle down to molecular resolution on ideal surfaces. These cycles are repeated until a layer with a specific thickness is achieved. Few materials are, however, ideal. During the early film growth precursors adsorb onto the surface and absorb into the near-surface regions depending both on the substrate and the deposition parameters. These precursors can react with the substrate affecting e.g. mechanical, barrier and surface properties. The deposited material starts then to form clusters leading to nonuniform early film growth. The purpose of this presentation is to demonstrate that thin and non-uniform layers can be used to tailor the surface characteristics of different substrates. For example, print quality (ink spreading and penetration) of inkjet printing on polymer films can be adjusted with metal oxide. Secondly, this can be used to control water penetration into porous nonwovens. Third example demonstrates how adhesion of extrusion coated biopolymer to inorganic oxides can be improved with a novel hybrid layer based on lactic acid. As the amount of material to be deposited is small, this will help to increase the speed in ALD/MLD processes designed for moving webs.

AB - Atomic and molecular layer deposition (ALD and MLD, respectively) techniques are examples of self-assembly based on repeated cycles of self-limiting gas-solid reactions. The precursors are pulsed into a reactor alternately, separated by inert gas pulses. During a single cycle, only one molecular layer is deposited on the surface, enabling tailored film composition in principle down to molecular resolution on ideal surfaces. These cycles are repeated until a layer with a specific thickness is achieved. Few materials are, however, ideal. During the early film growth precursors adsorb onto the surface and absorb into the near-surface regions depending both on the substrate and the deposition parameters. These precursors can react with the substrate affecting e.g. mechanical, barrier and surface properties. The deposited material starts then to form clusters leading to nonuniform early film growth. The purpose of this presentation is to demonstrate that thin and non-uniform layers can be used to tailor the surface characteristics of different substrates. For example, print quality (ink spreading and penetration) of inkjet printing on polymer films can be adjusted with metal oxide. Secondly, this can be used to control water penetration into porous nonwovens. Third example demonstrates how adhesion of extrusion coated biopolymer to inorganic oxides can be improved with a novel hybrid layer based on lactic acid. As the amount of material to be deposited is small, this will help to increase the speed in ALD/MLD processes designed for moving webs.

KW - adhesion

KW - ALd

KW - atomic layer deposition

KW - hybrid

KW - inorganic

KW - surface treatment

M3 - Conference Abstract

ER -

Vähä-Nissi M, Sievänen J, Salo E, Heikkilä P, Johansson L-S, Koskinen J et al. Atomic and molecular layer deposition for surface modification. 2013. Abstract from 7th International Conference on Materials for Advanced Technologies, ICMAT 2013, Singapore, Hong Kong.