Atomic Layer Deposition of PbS Thin Films at Low Temperatures

Georgi Popov; Goran Bačić; Miika Mattinen; Toni Manner; Hannu Lindström; Heli Seppänen; Sami Suihkonen; Marko Vehkamäki; Marianna Kemell; Pasi Jalkanen; Kenichiro Mizohata; Jyrki Räisänen; Markku Leskelä; Hanna Maarit Koivula; Seán T. Barry; Mikko Ritala

doi:10.1021/acs.chemmater.0c01887

Atomic Layer Deposition of PbS Thin Films at Low Temperatures

Georgi Popov (Corresponding Author), Goran Bačić, Miika Mattinen, Toni Manner, Hannu Lindström, Heli Seppänen, Sami Suihkonen, Marko Vehkamäki, Marianna Kemell, Pasi Jalkanen, Kenichiro Mizohata, Jyrki Räisänen, Markku Leskelä, Hanna Maarit Koivula, Seán T. Barry, Mikko Ritala (Corresponding Author)

BA6301 Optical measurements

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Abstract

Atomic layer deposition (ALD) is a viable method for depositing functional, passivating, and encapsulating layers on top of halide perovskites. Studies in that area have only focused on metal oxides, despite a great number of materials that can be made with ALD. This work demonstrates that, in addition to oxides, other ALD processes can be compatible with the perovskites. We describe two new ALD processes for lead sulfide. These processes operate at low deposition temperatures (45-155 °C) that have been inaccessible to previous ALD PbS processes. Our processes rely on volatile and reactive lead precursors Pb(dbda) (dbda = rac-N²,N³-di-tert-butylbutane-2,3-diamide) and Pb(btsa)₂ (btsa = bis(trimethylsilyl)amide) as well as H₂S. These precursors produce high quality PbS thin films that are uniform, crystalline, and pure. The films exhibit p-type conductivity and good mobilities of 10-70 cm² V^-1 s^-1. Low deposition temperatures enable direct ALD of PbS onto a halide perovskite CH₃NH₃PbI₃ (MAPI) without its decomposition. The stability of MAPI in ambient air is greatly improved by capping with ALD PbS. More generally, these new processes offer valuable alternatives for PbS-based devices, and we hope that this study will inspire more studies on ALD of non-oxides on halide perovskites.

Original language	English
Pages (from-to)	8216−8228
Journal	Chemistry of Materials
Volume	32
Issue number	19
DOIs	https://doi.org/10.1021/acs.chemmater.0c01887
Publication status	Published - 13 Oct 2020
MoE publication type	A1 Journal article-refereed

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Popov, G., Bačić, G., Mattinen, M., Manner, T., Lindström, H., Seppänen, H., Suihkonen, S., Vehkamäki, M., Kemell, M., Jalkanen, P., Mizohata, K., Räisänen, J., Leskelä, M., Koivula, H. M., Barry, S. T., & Ritala, M. (2020). Atomic Layer Deposition of PbS Thin Films at Low Temperatures. Chemistry of Materials, 32(19), 8216−8228. https://doi.org/10.1021/acs.chemmater.0c01887

Popov, Georgi ; Bačić, Goran ; Mattinen, Miika ; Manner, Toni ; Lindström, Hannu ; Seppänen, Heli ; Suihkonen, Sami ; Vehkamäki, Marko ; Kemell, Marianna ; Jalkanen, Pasi ; Mizohata, Kenichiro ; Räisänen, Jyrki ; Leskelä, Markku ; Koivula, Hanna Maarit ; Barry, Seán T. ; Ritala, Mikko. / Atomic Layer Deposition of PbS Thin Films at Low Temperatures. In: Chemistry of Materials. 2020 ; Vol. 32, No. 19. pp. 8216−8228.

@article{2c6420a7e82f433ab3b2026feed47039,

title = "Atomic Layer Deposition of PbS Thin Films at Low Temperatures",

abstract = "Atomic layer deposition (ALD) is a viable method for depositing functional, passivating, and encapsulating layers on top of halide perovskites. Studies in that area have only focused on metal oxides, despite a great number of materials that can be made with ALD. This work demonstrates that, in addition to oxides, other ALD processes can be compatible with the perovskites. We describe two new ALD processes for lead sulfide. These processes operate at low deposition temperatures (45-155 °C) that have been inaccessible to previous ALD PbS processes. Our processes rely on volatile and reactive lead precursors Pb(dbda) (dbda = rac-N2,N3-di-tert-butylbutane-2,3-diamide) and Pb(btsa)2 (btsa = bis(trimethylsilyl)amide) as well as H2S. These precursors produce high quality PbS thin films that are uniform, crystalline, and pure. The films exhibit p-type conductivity and good mobilities of 10-70 cm² V-1 s-1. Low deposition temperatures enable direct ALD of PbS onto a halide perovskite CH3NH3PbI3 (MAPI) without its decomposition. The stability of MAPI in ambient air is greatly improved by capping with ALD PbS. More generally, these new processes offer valuable alternatives for PbS-based devices, and we hope that this study will inspire more studies on ALD of non-oxides on halide perovskites.",

author = "Georgi Popov and Goran Ba{\v c}i{\'c} and Miika Mattinen and Toni Manner and Hannu Lindstr{\"o}m and Heli Sepp{\"a}nen and Sami Suihkonen and Marko Vehkam{\"a}ki and Marianna Kemell and Pasi Jalkanen and Kenichiro Mizohata and Jyrki R{\"a}is{\"a}nen and Markku Leskel{\"a} and Koivula, {Hanna Maarit} and Barry, {Se{\'a}n T.} and Mikko Ritala",

note = "Funding Information: We thank the Finnish Center of Excellence in Atomic Layer Deposition (ALDCoE 2012-2017) and additional support from the Academy of Finland (Decision Number 309552). We are grateful to the electron microscopy unit of the Institute of Biotechnology at the University of Helsinki for providing TEM instrument access. A part of the research was performed at the OtaNano - Micrometerova Nanofabrication Centre of Aalto University. G.P. acknowledges the doctoral program in Materials Research and Nanosciences (MATRENA) of the University of Helsinki as well as Emil Aaltonen foundation for funding and support. G.B. and S.T.B. acknowledge the QEII-OGSST program for funding and Carleton University for support. H.S. acknowledges the support from the Walter Ahlstr{\"o}m Foundation. Publisher Copyright: {\textcopyright} 2020 American Chemical Society. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.",

year = "2020",

month = oct,

day = "13",

doi = "10.1021/acs.chemmater.0c01887",

language = "English",

volume = "32",

pages = "8216−8228",

journal = "Chemistry of Materials",

issn = "0897-4756",

publisher = "American Chemical Society ACS",

number = "19",

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Popov, G, Bačić, G, Mattinen, M, Manner, T, Lindström, H, Seppänen, H, Suihkonen, S, Vehkamäki, M, Kemell, M, Jalkanen, P, Mizohata, K, Räisänen, J, Leskelä, M, Koivula, HM, Barry, ST & Ritala, M 2020, 'Atomic Layer Deposition of PbS Thin Films at Low Temperatures', Chemistry of Materials, vol. 32, no. 19, pp. 8216−8228. https://doi.org/10.1021/acs.chemmater.0c01887

Atomic Layer Deposition of PbS Thin Films at Low Temperatures. / Popov, Georgi (Corresponding Author); Bačić, Goran; Mattinen, Miika; Manner, Toni; Lindström, Hannu; Seppänen, Heli; Suihkonen, Sami; Vehkamäki, Marko; Kemell, Marianna; Jalkanen, Pasi; Mizohata, Kenichiro; Räisänen, Jyrki; Leskelä, Markku; Koivula, Hanna Maarit; Barry, Seán T.; Ritala, Mikko (Corresponding Author).

In: Chemistry of Materials, Vol. 32, No. 19, 13.10.2020, p. 8216−8228.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Atomic Layer Deposition of PbS Thin Films at Low Temperatures

AU - Popov, Georgi

AU - Bačić, Goran

AU - Mattinen, Miika

AU - Manner, Toni

AU - Lindström, Hannu

AU - Seppänen, Heli

AU - Suihkonen, Sami

AU - Vehkamäki, Marko

AU - Kemell, Marianna

AU - Jalkanen, Pasi

AU - Mizohata, Kenichiro

AU - Räisänen, Jyrki

AU - Leskelä, Markku

AU - Koivula, Hanna Maarit

AU - Barry, Seán T.

AU - Ritala, Mikko

N1 - Funding Information: We thank the Finnish Center of Excellence in Atomic Layer Deposition (ALDCoE 2012-2017) and additional support from the Academy of Finland (Decision Number 309552). We are grateful to the electron microscopy unit of the Institute of Biotechnology at the University of Helsinki for providing TEM instrument access. A part of the research was performed at the OtaNano - Micrometerova Nanofabrication Centre of Aalto University. G.P. acknowledges the doctoral program in Materials Research and Nanosciences (MATRENA) of the University of Helsinki as well as Emil Aaltonen foundation for funding and support. G.B. and S.T.B. acknowledge the QEII-OGSST program for funding and Carleton University for support. H.S. acknowledges the support from the Walter Ahlström Foundation. Publisher Copyright: © 2020 American Chemical Society. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.

PY - 2020/10/13

Y1 - 2020/10/13

N2 - Atomic layer deposition (ALD) is a viable method for depositing functional, passivating, and encapsulating layers on top of halide perovskites. Studies in that area have only focused on metal oxides, despite a great number of materials that can be made with ALD. This work demonstrates that, in addition to oxides, other ALD processes can be compatible with the perovskites. We describe two new ALD processes for lead sulfide. These processes operate at low deposition temperatures (45-155 °C) that have been inaccessible to previous ALD PbS processes. Our processes rely on volatile and reactive lead precursors Pb(dbda) (dbda = rac-N2,N3-di-tert-butylbutane-2,3-diamide) and Pb(btsa)2 (btsa = bis(trimethylsilyl)amide) as well as H2S. These precursors produce high quality PbS thin films that are uniform, crystalline, and pure. The films exhibit p-type conductivity and good mobilities of 10-70 cm² V-1 s-1. Low deposition temperatures enable direct ALD of PbS onto a halide perovskite CH3NH3PbI3 (MAPI) without its decomposition. The stability of MAPI in ambient air is greatly improved by capping with ALD PbS. More generally, these new processes offer valuable alternatives for PbS-based devices, and we hope that this study will inspire more studies on ALD of non-oxides on halide perovskites.

AB - Atomic layer deposition (ALD) is a viable method for depositing functional, passivating, and encapsulating layers on top of halide perovskites. Studies in that area have only focused on metal oxides, despite a great number of materials that can be made with ALD. This work demonstrates that, in addition to oxides, other ALD processes can be compatible with the perovskites. We describe two new ALD processes for lead sulfide. These processes operate at low deposition temperatures (45-155 °C) that have been inaccessible to previous ALD PbS processes. Our processes rely on volatile and reactive lead precursors Pb(dbda) (dbda = rac-N2,N3-di-tert-butylbutane-2,3-diamide) and Pb(btsa)2 (btsa = bis(trimethylsilyl)amide) as well as H2S. These precursors produce high quality PbS thin films that are uniform, crystalline, and pure. The films exhibit p-type conductivity and good mobilities of 10-70 cm² V-1 s-1. Low deposition temperatures enable direct ALD of PbS onto a halide perovskite CH3NH3PbI3 (MAPI) without its decomposition. The stability of MAPI in ambient air is greatly improved by capping with ALD PbS. More generally, these new processes offer valuable alternatives for PbS-based devices, and we hope that this study will inspire more studies on ALD of non-oxides on halide perovskites.

UR - http://www.scopus.com/inward/record.url?scp=85092065896&partnerID=8YFLogxK

U2 - 10.1021/acs.chemmater.0c01887

DO - 10.1021/acs.chemmater.0c01887

M3 - Article

AN - SCOPUS:85092065896

VL - 32

SP - 8216−8228

JO - Chemistry of Materials

JF - Chemistry of Materials

SN - 0897-4756

IS - 19

ER -

Atomic Layer Deposition of PbS Thin Films at Low Temperatures

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