Bis[(2-hydroxyethyl)dimethylammonium] Bis[u-acetato-O:O'-μ-(2-dimethylaminoethanolato-N, u-O)-μ3-oxotetraoxodiuranate[VI)]

Urho Turpeinen, Reino Hämäläinen, Ilpo Mutikainen, Olli Orama

Research output: Contribution to journalArticleScientificpeer-review

32 Citations (Scopus)

Abstract

In the centrosymmetric tetrameric [(UO2)4(O)2(C2H3O2)4(C4H10NO)2]2- anion {systematic name: bis([mu]-acetato)-1[kappa]O: 2[kappa]O': 3[kappa]O: 4[kappa]O'-bis(acetato)2[kappa]2O, O'; 4[kappa]2O, O'-bis([mu]-2-dimethylaminoethanolato)-1[kappa]2N, O: 4[kappa]O; 2[kappa]O: 3[kappa]2N, O-di-[mu]3-oxo-1:2:3[kappa]3O; 1:3:4[kappa]3O-tetrakis[dioxouranate(IV)]}, the U atoms are seven-coordinate, the shortest U...U distances being 3.681 (2), 3.775 (2) and 4.214 (2) Å and the longest 7.017 (2) Å. Four UO22+ ions are connected by two carboxylate groups, two ethanolato O atoms and two triply bridging O atoms. A (2-hydroxyethyl)dimethylammonium cation, C4H12NO+, links adjacent complex anions by N-H...O(uranyl) and O-H...O(acetate) hydrogen bonds.
Original languageEnglish
Pages (from-to)1169-1171
Number of pages3
JournalActa Crystallographica Section C: Crystal Structure Communications
VolumeC52
DOIs
Publication statusPublished - 1996
MoE publication typeA1 Journal article-refereed

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Atoms
Anions
Negative ions
anions
atoms
carboxylates
Cations
acetates
Hydrogen bonds
Acetates
Positive ions
Ions
hydrogen bonds
cations
ions

Cite this

@article{15c2e690f247455188e2d0baf5368753,
title = "Bis[(2-hydroxyethyl)dimethylammonium] Bis[u-acetato-O:O'-μ-(2-dimethylaminoethanolato-N, u-O)-μ3-oxotetraoxodiuranate[VI)]",
abstract = "In the centrosymmetric tetrameric [(UO2)4(O)2(C2H3O2)4(C4H10NO)2]2- anion {systematic name: bis([mu]-acetato)-1[kappa]O: 2[kappa]O': 3[kappa]O: 4[kappa]O'-bis(acetato)2[kappa]2O, O'; 4[kappa]2O, O'-bis([mu]-2-dimethylaminoethanolato)-1[kappa]2N, O: 4[kappa]O; 2[kappa]O: 3[kappa]2N, O-di-[mu]3-oxo-1:2:3[kappa]3O; 1:3:4[kappa]3O-tetrakis[dioxouranate(IV)]}, the U atoms are seven-coordinate, the shortest U...U distances being 3.681 (2), 3.775 (2) and 4.214 (2) {\AA} and the longest 7.017 (2) {\AA}. Four UO22+ ions are connected by two carboxylate groups, two ethanolato O atoms and two triply bridging O atoms. A (2-hydroxyethyl)dimethylammonium cation, C4H12NO+, links adjacent complex anions by N-H...O(uranyl) and O-H...O(acetate) hydrogen bonds.",
author = "Urho Turpeinen and Reino H{\"a}m{\"a}l{\"a}inen and Ilpo Mutikainen and Olli Orama",
note = "Project code: K6SU00074",
year = "1996",
doi = "10.1107/S0108270196000716",
language = "English",
volume = "C52",
pages = "1169--1171",
journal = "Acta Crystallographica Section C: Structural Chemistry",
issn = "2053-2296",
publisher = "Wiley",

}

Bis[(2-hydroxyethyl)dimethylammonium] Bis[u-acetato-O:O'-μ-(2-dimethylaminoethanolato-N, u-O)-μ3-oxotetraoxodiuranate[VI)]. / Turpeinen, Urho; Hämäläinen, Reino; Mutikainen, Ilpo; Orama, Olli.

In: Acta Crystallographica Section C: Crystal Structure Communications, Vol. C52, 1996, p. 1169-1171.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Bis[(2-hydroxyethyl)dimethylammonium] Bis[u-acetato-O:O'-μ-(2-dimethylaminoethanolato-N, u-O)-μ3-oxotetraoxodiuranate[VI)]

AU - Turpeinen, Urho

AU - Hämäläinen, Reino

AU - Mutikainen, Ilpo

AU - Orama, Olli

N1 - Project code: K6SU00074

PY - 1996

Y1 - 1996

N2 - In the centrosymmetric tetrameric [(UO2)4(O)2(C2H3O2)4(C4H10NO)2]2- anion {systematic name: bis([mu]-acetato)-1[kappa]O: 2[kappa]O': 3[kappa]O: 4[kappa]O'-bis(acetato)2[kappa]2O, O'; 4[kappa]2O, O'-bis([mu]-2-dimethylaminoethanolato)-1[kappa]2N, O: 4[kappa]O; 2[kappa]O: 3[kappa]2N, O-di-[mu]3-oxo-1:2:3[kappa]3O; 1:3:4[kappa]3O-tetrakis[dioxouranate(IV)]}, the U atoms are seven-coordinate, the shortest U...U distances being 3.681 (2), 3.775 (2) and 4.214 (2) Å and the longest 7.017 (2) Å. Four UO22+ ions are connected by two carboxylate groups, two ethanolato O atoms and two triply bridging O atoms. A (2-hydroxyethyl)dimethylammonium cation, C4H12NO+, links adjacent complex anions by N-H...O(uranyl) and O-H...O(acetate) hydrogen bonds.

AB - In the centrosymmetric tetrameric [(UO2)4(O)2(C2H3O2)4(C4H10NO)2]2- anion {systematic name: bis([mu]-acetato)-1[kappa]O: 2[kappa]O': 3[kappa]O: 4[kappa]O'-bis(acetato)2[kappa]2O, O'; 4[kappa]2O, O'-bis([mu]-2-dimethylaminoethanolato)-1[kappa]2N, O: 4[kappa]O; 2[kappa]O: 3[kappa]2N, O-di-[mu]3-oxo-1:2:3[kappa]3O; 1:3:4[kappa]3O-tetrakis[dioxouranate(IV)]}, the U atoms are seven-coordinate, the shortest U...U distances being 3.681 (2), 3.775 (2) and 4.214 (2) Å and the longest 7.017 (2) Å. Four UO22+ ions are connected by two carboxylate groups, two ethanolato O atoms and two triply bridging O atoms. A (2-hydroxyethyl)dimethylammonium cation, C4H12NO+, links adjacent complex anions by N-H...O(uranyl) and O-H...O(acetate) hydrogen bonds.

U2 - 10.1107/S0108270196000716

DO - 10.1107/S0108270196000716

M3 - Article

VL - C52

SP - 1169

EP - 1171

JO - Acta Crystallographica Section C: Structural Chemistry

JF - Acta Crystallographica Section C: Structural Chemistry

SN - 2053-2296

ER -