Abstract
Binaphthalenedicarboxamide zirconium complexes exhibit significantly enhanced catalytic activity in aminoalkene hydroamination reactions with respect to substrate scope (substrates without gem-dialkyl activation; cyclization of aminoheptenes), catalyst loading (as low as 0.5 mol %) and reaction temperatures (as low as 70 °C) compared to previous group 4 metal-based hydroamination catalyst systems.
Original language | English |
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Pages (from-to) | 24-27 |
Number of pages | 4 |
Journal | Organometallics |
Volume | 29 |
Issue number | 1 |
DOIs | |
Publication status | Published - 11 Jan 2010 |
MoE publication type | A1 Journal article-refereed |