C2-symmetric zirconium Bis(Amidate) complexes with enhanced reactivity in aminoalkene hydroamination

Alexander L. Reznichenko, Kai C. Hultzsch

Research output: Contribution to journalArticleScientificpeer-review

90 Citations (Scopus)

Abstract

Binaphthalenedicarboxamide zirconium complexes exhibit significantly enhanced catalytic activity in aminoalkene hydroamination reactions with respect to substrate scope (substrates without gem-dialkyl activation; cyclization of aminoheptenes), catalyst loading (as low as 0.5 mol %) and reaction temperatures (as low as 70 °C) compared to previous group 4 metal-based hydroamination catalyst systems.

Original languageEnglish
Pages (from-to)24-27
Number of pages4
JournalOrganometallics
Volume29
Issue number1
DOIs
Publication statusPublished - 11 Jan 2010
MoE publication typeA1 Journal article-refereed

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