Carbon formation in catalytic steam reforming of natural gas with SOFC anode off-gas

Johanna Kihlman, Juli Sucipto, Noora Kaisalo, Pekka Simell, Juha Lehtonen

Research output: Contribution to journalArticleScientificpeer-review

17 Citations (Scopus)

Abstract

Natural gas was reformed with anode off-gas of a solid oxide fuel cell (SOFC) in a laboratory reactor using model gases. Nickel and precious metal catalysts were tested at 650 °C and 700 °C inlet temperature. The oxygen to carbon (O/C) molar ratio of the inlet gas was varied between 0.3 and 2.0 to find out the limit O/C ratio for carbon formation. Two natural gas compositions were used: low purity Danish gas and high purity Russian gas. The experimental limit was found to be 0.9-1.25 for nickel catalyst and 0.5-0.75 for precious metal catalyst. The limit was higher with Danish gas than with Russian gas in the experiments with nickel catalyst but this effect was not observed with the precious metal catalyst. A good correlation between experimental results and thermodynamic calculations was found using the principle of actual gas: the calculations estimated the O/C limit ratio for nickel at 1.0 and for precious metal catalyst between 0.5 and 0.7.
Original languageEnglish
Pages (from-to)1548-1558
JournalInternational Journal of Hydrogen Energy
Volume40
Issue number3
DOIs
Publication statusPublished - 2015
MoE publication typeA1 Journal article-refereed

Keywords

  • anode off-gas recycling
  • reforming
  • precious metal catalyst
  • nickel catalyst
  • carbon formation
  • solid oxide fuel cell

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