Catalyst Screening and Kinetic Modeling for CO Production by High Pressure and Temperature Reverse Water Gas Shift for Fischer-Tropsch Applications

Francisco Vidal Vázquez (Corresponding Author), Peter Pfeifer, Juha Lehtonen, Paolo Piermartini, Pekka Simell, Ville Alopaeus

    Research output: Contribution to journalArticleScientificpeer-review

    17 Citations (Scopus)

    Abstract

    In this work, catalyst screening and reaction kinetic modeling are performed for two Ni-based and one Rh-based commercial catalysts for a reverse water gas shift (rWGS) reaction under atmospheric and 30 bar a pressure. Ni-based catalysts displayed higher activity compared to Rh-based catalysts despite the severe initial deactivation Ni-based catalysts suffered, which increases catalyst selectivity toward CO formation. Ni/Al 2O 3 catalyst with lower Ni content (2 w-%) exhibited higher selectivity toward CO formation compared to the Ni/Al 2O 3 catalyst with higher Ni content (15 wt %). The Ni/Al 2O 3 (2 wt % of Ni) catalyst was further tested for kinetic modeling. Three kinetic models were developed based on reaction mechanisms and kinetic models obtained from other publications for rWGS/WGS, methanation, and methane steam reforming reactions based on different mechanistic approaches. The model based on mechanistic assumptions originally proposed by Xu and Froment was concluded to be the most suitable to describe the high temperature reaction system of the rWGS and methanation over supported nickel catalyst. On the basis of statistical analysis, the model proposed by Xu and Froment was also concluded to be the best for the catalyst and reaction system studied in this work.

    Original languageEnglish
    Pages (from-to)13262–13272
    Number of pages11
    JournalIndustrial & Engineering Chemistry Research: Tapio Salmi Festschrift
    Volume56
    Issue number45
    Early online date2017
    DOIs
    Publication statusPublished - 3 Jul 2017
    MoE publication typeA1 Journal article-refereed

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    • Neo-Carbon Energy

      Vainikka, P., Breyer, C., Partanen, J., Heinonen, S., Simell, P. & Ahola, J.

      1/01/1431/12/17

      Project: Business Finland project

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