Catalytic σ-bond metathesis

Alexander L. Reznichenko, Kai C. Hultzsch

Research output: Chapter in Book/Report/Conference proceedingChapter or book articleScientificpeer-review

24 Citations (Scopus)

Abstract

This account summarizes information on recently reported applications of organo-rare-earth metal complexes in various catalytic transformations of small molecules. The σ-bond metathesis at d0rare-earth metal centers plays a pivotal role in carbon-carbon and carbon-heteroatom bond forming processes. Relevant mechanistic details are discussed and the focus of the review lies in practical applications of organo-rare-earth metal complexes.

Original languageEnglish
Title of host publicationMolecular Catalysis of Rare-Earth Elements
EditorsPeter W. Roesky
PublisherSpringer
Pages1-48
ISBN (Print)9783642128103
DOIs
Publication statusPublished - 2010
MoE publication typeA3 Part of a book or another research book

Publication series

SeriesStructure and Bonding
Volume137
ISSN0081-5993

Keywords

  • C-H activation
  • Catalysis
  • Cyclization
  • Hydroalkoxylation
  • Hydroamination
  • Hydroboration
  • Hydrogenation
  • Hydrophosphination
  • Hydrosilylation
  • Hydrostannation

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