Catalytic decomposition of gasification gas tar with benzene as the model compound

Pekka Simell (Corresponding Author), N. Hakala, H. Haario, A. Krause

Research output: Contribution to journalArticleScientificpeer-review

77 Citations (Scopus)

Abstract

Tar decomposition over dolomite catalyst in gasification conditions was modeled by benzene reaction with CO2. Kinetic studies were carried out at 1023−1173 K and ambient pressure in a plug flow reactor. Operation conditions without external or internal mass transfer limitations were used. Mechanistic models of the Langmuir−Hinshelwood type describing benzene decomposition were derived and tested. Experimental results could be best described by a kinetic equation where benzene single-site adsorption on dolomite was the rate-determining step and CO2 adsorption took place nondissociatively.

Original languageEnglish
Pages (from-to)42 - 45
Number of pages4
JournalIndustrial & Engineering Chemistry Research
Volume36
Issue number1
DOIs
Publication statusPublished - 1997
MoE publication typeA1 Journal article-refereed

Keywords

  • gasification

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