Catalytic fast pyrolysis: Influencing bio-oil quality with the catalyst-to-biomass ratio

Ville Paasikallio (Corresponding Author), Konstantinos Kalogiannis, Angelos Lappas, Jani Lehto, Juha Lehtonen

    Research output: Contribution to journalArticleScientificpeer-review

    43 Citations (Scopus)


    In situ catalytic fast pyrolysis can be used to produce partially upgraded bio-oils. This process, however, suffers from rapid catalyst deactivation caused by coke formation, which necessitates the use of continuous catalyst regeneration. This can be achieved by using a circulating fluidized-bed reactor. In such a reactor, one key operational variable is the catalyst-to-biomass (C/B) ratio, which influences the extent of the catalytic reactions that take place. In this study, woody biomass is pyrolyzed in a pilot-scale circulating fluidized-bed reactor system using a HZSM-5 zeolite with varying C/B ratios. The C/B ratio influences the overall product distribution, the elemental distribution, and the characteristics of the liquid products. An increase of the C/B ratio enhances the conversion of pyrolysis vapors but this does not result in a continuous improvement in bio-oil quality. The C/B ratio is, nevertheless, a factor that can be used to optimize the catalytic fast pyrolysis process.
    Original languageEnglish
    Pages (from-to)94-103
    JournalEnergy Technology
    Issue number1
    Publication statusPublished - 2017
    MoE publication typeA1 Journal article-refereed


    • biofuels
    • biomass
    • bio-oil
    • catalytic fast pyrolysis
    • zeolites


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