Catalytic upgrading of co-pyrolysis oils from bisphenol A polycarbonate and lignins

M Brebu; Tarja Tamminen; L Hannevold; M Stöcker; I Spiridon

doi:10.1016/j.polymdegradstab.2014.01.035

Catalytic upgrading of co-pyrolysis oils from bisphenol A polycarbonate and lignins

M Brebu (Corresponding Author), Tarja Tamminen, L Hannevold, M Stöcker, I Spiridon

BA3505 Biorefining chemistry

Research output: Contribution to journal › Article › Scientific › peer-review

6 Citations (Scopus)

Abstract

Co-pyrolysis of bisphenol A polycarbonate with lignoboost (regular and modified) lignin from softwood and with organosolv lignin from hardwood was performed in a semi-batch reactor at 500 °C and self-generated pressure. Catalytic upgrading was performed at 300 °C over MCM-41 and SBA-15 catalysts. The effect consisted in conversion of bisphenol A into phenol and its light derivatives. Hydrogenation occurred during upgrading based on the hydrocarbons converted into coke on the surface of catalysts. The Al-MCM41 with Si/Al ratio of 16 (MCM16) and Al-SBA-15 with Si/Al ratio of 48 (SBA 48) catalysts had similar effects for the lignoboost lignins, with slight advantage for the MCM16 in the case of regular lignoboost while MCM16 was clearly the best one for the organosolv lignin in converting the heavier compounds into lighter ones

Original language	English
Pages (from-to)	88-94
Journal	Polymer Degradation and Stability
Volume	102
DOIs	https://doi.org/10.1016/j.polymdegradstab.2014.01.035
Publication status	Published - 2014
MoE publication type	A1 Journal article-refereed

Keywords

Catalysts
co-pyrolysis
lignin
polycarbonate
upgrading

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@article{bf70949df7524369b4b876993531387b,

title = "Catalytic upgrading of co-pyrolysis oils from bisphenol A polycarbonate and lignins",

abstract = "Co-pyrolysis of bisphenol A polycarbonate with lignoboost (regular and modified) lignin from softwood and with organosolv lignin from hardwood was performed in a semi-batch reactor at 500 °C and self-generated pressure. Catalytic upgrading was performed at 300 °C over MCM-41 and SBA-15 catalysts. The effect consisted in conversion of bisphenol A into phenol and its light derivatives. Hydrogenation occurred during upgrading based on the hydrocarbons converted into coke on the surface of catalysts. The Al-MCM41 with Si/Al ratio of 16 (MCM16) and Al-SBA-15 with Si/Al ratio of 48 (SBA 48) catalysts had similar effects for the lignoboost lignins, with slight advantage for the MCM16 in the case of regular lignoboost while MCM16 was clearly the best one for the organosolv lignin in converting the heavier compounds into lighter ones",

keywords = "Catalysts, co-pyrolysis, lignin, polycarbonate, upgrading",

author = "M Brebu and Tarja Tamminen and L Hannevold and M St{\"o}cker and I Spiridon",

year = "2014",

doi = "10.1016/j.polymdegradstab.2014.01.035",

language = "English",

volume = "102",

pages = "88--94",

journal = "Polymer Degradation and Stability",

issn = "0141-3910",

publisher = "Elsevier",

}

TY - JOUR

T1 - Catalytic upgrading of co-pyrolysis oils from bisphenol A polycarbonate and lignins

AU - Brebu, M

AU - Tamminen, Tarja

AU - Hannevold, L

AU - Stöcker, M

AU - Spiridon, I

PY - 2014

Y1 - 2014

N2 - Co-pyrolysis of bisphenol A polycarbonate with lignoboost (regular and modified) lignin from softwood and with organosolv lignin from hardwood was performed in a semi-batch reactor at 500 °C and self-generated pressure. Catalytic upgrading was performed at 300 °C over MCM-41 and SBA-15 catalysts. The effect consisted in conversion of bisphenol A into phenol and its light derivatives. Hydrogenation occurred during upgrading based on the hydrocarbons converted into coke on the surface of catalysts. The Al-MCM41 with Si/Al ratio of 16 (MCM16) and Al-SBA-15 with Si/Al ratio of 48 (SBA 48) catalysts had similar effects for the lignoboost lignins, with slight advantage for the MCM16 in the case of regular lignoboost while MCM16 was clearly the best one for the organosolv lignin in converting the heavier compounds into lighter ones

AB - Co-pyrolysis of bisphenol A polycarbonate with lignoboost (regular and modified) lignin from softwood and with organosolv lignin from hardwood was performed in a semi-batch reactor at 500 °C and self-generated pressure. Catalytic upgrading was performed at 300 °C over MCM-41 and SBA-15 catalysts. The effect consisted in conversion of bisphenol A into phenol and its light derivatives. Hydrogenation occurred during upgrading based on the hydrocarbons converted into coke on the surface of catalysts. The Al-MCM41 with Si/Al ratio of 16 (MCM16) and Al-SBA-15 with Si/Al ratio of 48 (SBA 48) catalysts had similar effects for the lignoboost lignins, with slight advantage for the MCM16 in the case of regular lignoboost while MCM16 was clearly the best one for the organosolv lignin in converting the heavier compounds into lighter ones

KW - Catalysts

KW - co-pyrolysis

KW - lignin

KW - polycarbonate

KW - upgrading

U2 - 10.1016/j.polymdegradstab.2014.01.035

DO - 10.1016/j.polymdegradstab.2014.01.035

M3 - Article

VL - 102

SP - 88

EP - 94

JO - Polymer Degradation and Stability

JF - Polymer Degradation and Stability

SN - 0141-3910

ER -