Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions

Esther Quintanilla; Fabio Di Lena; Peter Chen

doi:10.1039/b607248h

Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions

Esther Quintanilla
, Fabio Di Lena
, Peter Chen^*

^*Corresponding author for this work

Not published at VTT

Swiss Federal Institute of Technology in Zurich (ETH Zürich)

Research output: Contribution to journal › Article › Scientific › peer-review

36 Citations (Scopus)

Abstract

Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.

Original language	English
Pages (from-to)	4309-4311
Number of pages	3
Journal	Chemical Communications
Issue number	41
DOIs	https://doi.org/10.1039/b607248h
Publication status	Published - 2006
MoE publication type	A1 Journal article-refereed

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title = "Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions",

abstract = "Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.",

author = "Esther Quintanilla and \{Di Lena\}, Fabio and Peter Chen",

year = "2006",

doi = "10.1039/b607248h",

language = "English",

pages = "4309--4311",

journal = "Chemical Communications",

issn = "1359-7345",

publisher = "Royal Society of Chemistry RSC",

number = "41",

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TY - JOUR

T1 - Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions

AU - Quintanilla, Esther

AU - Di Lena, Fabio

AU - Chen, Peter

PY - 2006

Y1 - 2006

N2 - Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.

AB - Chemical trapping of metal-bound oligomeric chains during the MAO-activated, metallocene-catalyzed polymerization of ethylene identify the two observed chain-bearing species to be alkylzirconocenium species and higher alkyl aluminiums, consistent with a proposed mechanism.

UR - https://www.scopus.com/pages/publications/33750079531

U2 - 10.1039/b607248h

DO - 10.1039/b607248h

M3 - Article

AN - SCOPUS:33750079531

SN - 1359-7345

SP - 4309

EP - 4311

JO - Chemical Communications

JF - Chemical Communications

IS - 41

ER -

Chain transfer to aluminium in MAO-activated metallocene-catalyzed polymerization reactions

Abstract

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