Characterization of biomass-based flash pyrolysis oils

Kai Sipilä*, Eeva Kuoppala, Leena Fagernäs, Anja Oasmaa

*Corresponding author for this work

    Research output: Contribution to journalArticleScientificpeer-review

    400 Citations (Scopus)

    Abstract

    An analytical scheme for the characterization of biomass-based flash pyrolysis oils was developed. The scheme was based on fractionation of the oils with water and on further extraction of the water-soluble fraction with diethylether. The chemical composition of the fractions was analyzed by gas chromatography-mass spectrometry. The physical and chemical nature of straw, pine and hardwood pyrolysis oils was determined and compared with each other. Correlations between the physical properties and chemical composition of the oils were drawn. The characterization method will be utilized in further work for stabilization and upgrading tests of flash pyrolysis oils.

    Original languageEnglish
    Pages (from-to)103-113
    Number of pages11
    JournalBiomass and Bioenergy
    Volume14
    Issue number2
    DOIs
    Publication statusPublished - 23 Mar 1998
    MoE publication typeA1 Journal article-refereed

    Funding

    Financial support from the Technology Development Center Finland (Tekes) through the Bioenergy Research Program (BIOENERGIA) and from the Finnish Corporations Vapo Oy, Wärtsilä Diesel Ltd, Metsä-Serla Oy, and Neste Oy is gratefully acknowledged. Thanks are also due to Ms Johanna Levander, Mrs Raili Silvasti and Mrs Sirkka Huru of VTT for skillful technical assistance, to Mr Vesa Arpiainen of VTT for producing the straw and pine pyrolysis oil samples, and to Mr Eero Leppämäki of VTT for analytical advice. Ensyn Technologies Inc. is acknowledged for providing the hardwood pyrolysis oil sample.

    Keywords

    • Bio-oil
    • Characterization
    • Composition
    • Properties
    • Pyrolysis oil

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