Characterization of hydrotreated fast pyrolysis liquids

A. Oasmaa; E. Kuoppala; A. Ardiyanti; R. H. Venderbosch; H. J. Heeres

doi:10.1021/ef100573q

Characterization of hydrotreated fast pyrolysis liquids

A. Oasmaa, E. Kuoppala, A. Ardiyanti, R. H. Venderbosch, H. J. Heeres

BA3603 Thermochemical conversions

Research output: Contribution to journal › Article › Scientific › peer-review

83 Citations (Scopus)

Abstract

This paper focuses on analytical methods to determine the composition of hydrotreated fast pyrolysis liquids. With this information, it is possible to gain insights in the chemical transformations taking place during catalytic hydrotreatment (hydrogenation and/or hydrodeoxygenation, HDO) of pyrolysis liquids. Three different samples, produced at different hydrotreatment severity levels (defined by temperature and residence time) using Ru/C as the catalyst, were analyzed in detail. The composition of the products was determined by solvent fractionation followed by detailed analysis of the various fractions by gas cheromatography/mass selective detector (GC/MSD), capillary electrophoresis (CE), and NMR (¹H NMR, ¹³C NMR, and ³¹P NMR). The decrease in the carbohydrate fraction was easily followed by the Brix method after solvent fractionation.

Original language	English
Pages (from-to)	5264-5272
Number of pages	9
Journal	Energy & Fuels
Volume	24
Issue number	9
DOIs	https://doi.org/10.1021/ef100573q
Publication status	Published - 16 Sep 2010
MoE publication type	A1 Journal article-refereed

Access to Document

10.1021/ef100573q

Link to publication in Scopus

Fingerprint Dive into the research topics of 'Characterization of hydrotreated fast pyrolysis liquids'. Together they form a unique fingerprint.

Cite this

@article{4c9afee7bc22447d97046dd4aaa8679f,

title = "Characterization of hydrotreated fast pyrolysis liquids",

abstract = "This paper focuses on analytical methods to determine the composition of hydrotreated fast pyrolysis liquids. With this information, it is possible to gain insights in the chemical transformations taking place during catalytic hydrotreatment (hydrogenation and/or hydrodeoxygenation, HDO) of pyrolysis liquids. Three different samples, produced at different hydrotreatment severity levels (defined by temperature and residence time) using Ru/C as the catalyst, were analyzed in detail. The composition of the products was determined by solvent fractionation followed by detailed analysis of the various fractions by gas cheromatography/mass selective detector (GC/MSD), capillary electrophoresis (CE), and NMR (1H NMR, 13C NMR, and 31P NMR). The decrease in the carbohydrate fraction was easily followed by the Brix method after solvent fractionation.",

author = "A. Oasmaa and E. Kuoppala and A. Ardiyanti and Venderbosch, {R. H.} and Heeres, {H. J.}",

year = "2010",

month = sep,

day = "16",

doi = "10.1021/ef100573q",

language = "English",

volume = "24",

pages = "5264--5272",

journal = "Energy & Fuels",

issn = "0887-0624",

publisher = "American Chemical Society ACS",

number = "9",

}

TY - JOUR

T1 - Characterization of hydrotreated fast pyrolysis liquids

AU - Oasmaa, A.

AU - Kuoppala, E.

AU - Ardiyanti, A.

AU - Venderbosch, R. H.

AU - Heeres, H. J.

PY - 2010/9/16

Y1 - 2010/9/16

N2 - This paper focuses on analytical methods to determine the composition of hydrotreated fast pyrolysis liquids. With this information, it is possible to gain insights in the chemical transformations taking place during catalytic hydrotreatment (hydrogenation and/or hydrodeoxygenation, HDO) of pyrolysis liquids. Three different samples, produced at different hydrotreatment severity levels (defined by temperature and residence time) using Ru/C as the catalyst, were analyzed in detail. The composition of the products was determined by solvent fractionation followed by detailed analysis of the various fractions by gas cheromatography/mass selective detector (GC/MSD), capillary electrophoresis (CE), and NMR (1H NMR, 13C NMR, and 31P NMR). The decrease in the carbohydrate fraction was easily followed by the Brix method after solvent fractionation.

AB - This paper focuses on analytical methods to determine the composition of hydrotreated fast pyrolysis liquids. With this information, it is possible to gain insights in the chemical transformations taking place during catalytic hydrotreatment (hydrogenation and/or hydrodeoxygenation, HDO) of pyrolysis liquids. Three different samples, produced at different hydrotreatment severity levels (defined by temperature and residence time) using Ru/C as the catalyst, were analyzed in detail. The composition of the products was determined by solvent fractionation followed by detailed analysis of the various fractions by gas cheromatography/mass selective detector (GC/MSD), capillary electrophoresis (CE), and NMR (1H NMR, 13C NMR, and 31P NMR). The decrease in the carbohydrate fraction was easily followed by the Brix method after solvent fractionation.

UR - http://www.scopus.com/inward/record.url?scp=77956740049&partnerID=8YFLogxK

U2 - 10.1021/ef100573q

DO - 10.1021/ef100573q

M3 - Article

VL - 24

SP - 5264

EP - 5272

JO - Energy & Fuels

JF - Energy & Fuels

SN - 0887-0624

IS - 9

ER -