Characterization of the europium substituted superconducting Bi2Sr2CaCu2O8+y phase

Maarit Karppinen, Olli Antson, P. Baules, Tarja Karlemo, T. Katila, Juha Linden, M. Lippmaa, Lauri Niinistö, C. Roucau, I. Tittonen, Kari Ullakko

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    Abstract

    Effects of europium substitution on the stoichiometry, structure and superconductivity of the Bi2Sr2CaCu2O8+y phase have been investigated. Partial replacement by calcium by europium promotes the single-phase formation and leads to an uptake of extra oxygen into the structure.
    Oxygen content in the Bi2Sr2Ca1-xEuxCu2O8+y materials was determined by the thermogravimetric hydrogen reduction method. In an attempt to locate the intercalated oxygen atoms, X-ray, neutron and electron diffraction techniques were used. In addition, the samples were characterized by AC magnetic susceptibility measurements as well as by 151Eu Mossbauer spectroscopy.
    The applicability of these methods and the results obtained thereby are discussed
    Original languageEnglish
    Pages (from-to)476-481
    JournalSuperconductor Science and Technology
    Volume5
    Issue number8
    DOIs
    Publication statusPublished - 1992
    MoE publication typeA1 Journal article-refereed

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  • Cite this

    Karppinen, M., Antson, O., Baules, P., Karlemo, T., Katila, T., Linden, J., Lippmaa, M., Niinistö, L., Roucau, C., Tittonen, I., & Ullakko, K. (1992). Characterization of the europium substituted superconducting Bi2Sr2CaCu2O8+y phase. Superconductor Science and Technology, 5(8), 476-481. https://doi.org/10.1088/0953-2048/5/8/004