Chemical oxidation of polyacetylene by cupric chloride

Jan-Erik Österholm; Heikki Isotalo; Henrik Stubb

doi:10.1080/00268948508074606

Chemical oxidation of polyacetylene by cupric chloride

Jan-Erik Österholm, Heikki Isotalo, Henrik Stubb

VTT Technical Research Centre of Finland

Neste Oyj

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

Polyacetylene, (CH)_X, has been oxidized (doped) by CuCl₂ to give highly conducting charge-transfer complexes. Conductivities of highly doped films range from 30 to 80 Scm⁻¹ corresponding to y = 0.06 – 0.12. In lightly doped samples a rapid decrease in the activation energy of conduction is observed with increasing dopant concentration as well as the appearence of the typical dopant-associated IR-absorptions. Doping is believed to proceed via a partial reduction of CuCl₂ and the insertion of stabilizing anions such as CuCl⁻ ₃.

Original language	English
Pages (from-to)	107-112
Journal	Molecular Crystals and Liquid Crystals
Volume	117
Issue number	1
DOIs	https://doi.org/10.1080/00268948508074606
Publication status	Published - 1985
MoE publication type	A1 Journal article-refereed

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title = "Chemical oxidation of polyacetylene by cupric chloride",

abstract = "Polyacetylene, (CH)X, has been oxidized (doped) by CuCl2 to give highly conducting charge-transfer complexes. Conductivities of highly doped films range from 30 to 80 Scm−1 corresponding to y = 0.06 – 0.12. In lightly doped samples a rapid decrease in the activation energy of conduction is observed with increasing dopant concentration as well as the appearence of the typical dopant-associated IR-absorptions. Doping is believed to proceed via a partial reduction of CuCl2 and the insertion of stabilizing anions such as CuCl− 3. ",

author = "Jan-Erik {\"O}sterholm and Heikki Isotalo and Henrik Stubb",

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AU - Österholm, Jan-Erik

AU - Isotalo, Heikki

AU - Stubb, Henrik

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N2 - Polyacetylene, (CH)X, has been oxidized (doped) by CuCl2 to give highly conducting charge-transfer complexes. Conductivities of highly doped films range from 30 to 80 Scm−1 corresponding to y = 0.06 – 0.12. In lightly doped samples a rapid decrease in the activation energy of conduction is observed with increasing dopant concentration as well as the appearence of the typical dopant-associated IR-absorptions. Doping is believed to proceed via a partial reduction of CuCl2 and the insertion of stabilizing anions such as CuCl− 3.

AB - Polyacetylene, (CH)X, has been oxidized (doped) by CuCl2 to give highly conducting charge-transfer complexes. Conductivities of highly doped films range from 30 to 80 Scm−1 corresponding to y = 0.06 – 0.12. In lightly doped samples a rapid decrease in the activation energy of conduction is observed with increasing dopant concentration as well as the appearence of the typical dopant-associated IR-absorptions. Doping is believed to proceed via a partial reduction of CuCl2 and the insertion of stabilizing anions such as CuCl− 3.

U2 - 10.1080/00268948508074606

DO - 10.1080/00268948508074606

M3 - Article

SN - 1542-1406

VL - 117

SP - 107

EP - 112

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 1

ER -

Chemical oxidation of polyacetylene by cupric chloride

Abstract

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