Chemical Recovery of γ-Valerolactone/Water Biorefinery

Huy Quang Lê, Juha Pekka Pokki, Marc Borrega, Petri Uusi-Kyyny, Ville Alopaeus, Herbert Sixta (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

3 Citations (Scopus)

Abstract

We introduce the optimization of the pulping conditions and propose different chemical recovery options for a proven biorefinery concept based on γ-valerolactone (GVL)/water fractionation. The pulping process has been optimized whereby the liquor-to-wood (L:W) ratio could be reduced to 3 L/kg without compromising the pulp properties as raw material for textile fibers production. The recovery of the pulping solvent was performed through combinations of lignin precipitation by water addition, distillation at reduced pressure, and liquid CO2 extraction. With a two-step lignin precipitation coupled with vacuum distillation, more than 90% of lignin and GVL could be recovered from the spent liquor. However, a significant part of GVL remained unrecoverable in the residue, which was a highly viscous liquid with complicated phase behavior. The recovery by lignin precipitation combined with liquid CO2 extraction could recover more than 85% GVL and 90% lignin without forming any problematic residue as in the distillation process. The remaining GVL remained in the raffinate containing a low amount of lignin and other compounds, which can be further processed to isolate the GVL and improve the recovery rate.

Original languageEnglish
Pages (from-to)15147–15158
Number of pages12
JournalIndustrial and Engineering Chemistry Research
Volume57
Issue number44
DOIs
Publication statusPublished - 18 Oct 2018
MoE publication typeNot Eligible

Fingerprint

Lignin
Recovery
Water
Distillation
Liquids
Textile fibers
Phase behavior
Fractionation
Pulp
Wood
Raw materials
Vacuum

Keywords

  • carbon dioxide
  • distillation
  • lignin
  • liquids
  • recovery
  • refining
  • chemical recovery
  • pulp properties

Cite this

Lê, H. Q., Pokki, J. P., Borrega, M., Uusi-Kyyny, P., Alopaeus, V., & Sixta, H. (2018). Chemical Recovery of γ-Valerolactone/Water Biorefinery. Industrial and Engineering Chemistry Research, 57(44), 15147–15158. https://doi.org/10.1021/acs.iecr.8b03723
Lê, Huy Quang ; Pokki, Juha Pekka ; Borrega, Marc ; Uusi-Kyyny, Petri ; Alopaeus, Ville ; Sixta, Herbert. / Chemical Recovery of γ-Valerolactone/Water Biorefinery. In: Industrial and Engineering Chemistry Research. 2018 ; Vol. 57, No. 44. pp. 15147–15158.
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Lê, HQ, Pokki, JP, Borrega, M, Uusi-Kyyny, P, Alopaeus, V & Sixta, H 2018, 'Chemical Recovery of γ-Valerolactone/Water Biorefinery', Industrial and Engineering Chemistry Research, vol. 57, no. 44, pp. 15147–15158. https://doi.org/10.1021/acs.iecr.8b03723

Chemical Recovery of γ-Valerolactone/Water Biorefinery. / Lê, Huy Quang; Pokki, Juha Pekka; Borrega, Marc; Uusi-Kyyny, Petri; Alopaeus, Ville; Sixta, Herbert (Corresponding Author).

In: Industrial and Engineering Chemistry Research, Vol. 57, No. 44, 18.10.2018, p. 15147–15158.

Research output: Contribution to journalArticleScientificpeer-review

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