Chitosan-metal and metal oxide nanocomposites for active and intelligent food packaging; a comprehensive review of emerging trends and associated challenges

In recent years, significant advancements in biopolymer-based packaging have emerged as a response to the environmental challenges posed by traditional petroleum-based materials. The drive for sustainable, renewable, and degradable alternatives to fossil-based components in the packaging industry has led to an increased focus on chitosan, the second most abundant biopolymer after cellulose. Chitosan offers intrinsic properties such as biodegradability, biocompatibility, antimicrobial activity, excellent barrier and film-forming capabilities, positioning it as an ideal candidate for food packaging applications. However, limitations including inferior mechanical, thermal, barrier properties, and brittleness compared to conventional plastics have limiting its widespread adoption in the food packaging industry. Chitosan has been extensively utilized in various forms, particularly as nanocomposites incorporating metal nanoparticles, leading to chitosan-based nanocomposite films/coatings that synergistically combine the advantageous properties of both chitosan and metal nanoparticles. Through an in-depth analysis of the current research (primarily the last 5 years), this review delves into the physicochemical, mechanical, sensing, and antimicrobial properties of chitosan nanocomposite as an innovative food packaging material. This review will provide insights into the potential toxicity and environmental impact of nanoparticle migration, as well as the prospects and challenges associated with chitosan-metal/metal oxide nanocomposite films in the development of sustainable packaging solutions.