cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate

L. Russo, Kalle Nättinen, V. Vertlib, J. Rodrigues, Kalle Rissanen (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

Abstract

The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis­(diphenyl­phosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.
Original languageEnglish
Pages (from-to)m2052-m2053
JournalActa Crystallographica Section E: Crystallographic Communications
Volume62
Issue number9
DOIs
Publication statusPublished - 2006
MoE publication typeA1 Journal article-refereed

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Ruthenium
Methylene Chloride
Methane
Dichloromethane
ruthenium
methane
Ligands
ligands
Chemical bonds
Metals
wire
Wire
metals

Cite this

Russo, L. ; Nättinen, Kalle ; Vertlib, V. ; Rodrigues, J. ; Rissanen, Kalle. / cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate. In: Acta Crystallographica Section E: Crystallographic Communications. 2006 ; Vol. 62, No. 9. pp. m2052-m2053.
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abstract = "The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis­(diphenyl­phosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.",
author = "L. Russo and Kalle N{\"a}ttinen and V. Vertlib and J. Rodrigues and Kalle Rissanen",
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cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate. / Russo, L.; Nättinen, Kalle; Vertlib, V.; Rodrigues, J.; Rissanen, Kalle (Corresponding Author).

In: Acta Crystallographica Section E: Crystallographic Communications, Vol. 62, No. 9, 2006, p. m2052-m2053.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate

AU - Russo, L.

AU - Nättinen, Kalle

AU - Vertlib, V.

AU - Rodrigues, J.

AU - Rissanen, Kalle

PY - 2006

Y1 - 2006

N2 - The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis­(diphenyl­phosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

AB - The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis­(diphenyl­phosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium mol­ecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

U2 - 10.1107/S160053680602900X

DO - 10.1107/S160053680602900X

M3 - Article

VL - 62

SP - m2052-m2053

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

SN - 2056-9890

IS - 9

ER -