cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate

L. Russo; Kalle Nättinen; V. Vertlib; J. Rodrigues; Kalle Rissanen

doi:10.1107/S160053680602900X

cis-Diazido[bis(diphenylphosphino)methane-κ²P,P']ruthenium(II) dichloromethane 0.42-solvate

L. Russo
, Kalle Nättinen
, V. Vertlib
, J. Rodrigues
, Kalle Rissanen^*

^*Corresponding author for this work

VTT Technical Research Centre of Finland

Research output: Contribution to journal › Article › Scientific › peer-review

Abstract

The title compound, [Ru(N₃)2(C₂₅H₂₂P₂)₂] or cis-[Ru(N₃)₂(dppm)₂] [dppm is bis(diphenylphosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium molecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

Original language	English
Pages (from-to)	m2052-m2053
Journal	Acta Crystallographica Section E: Crystallographic Communications
Volume	62
Issue number	9
DOIs	https://doi.org/10.1107/S160053680602900X
Publication status	Published - 2006
MoE publication type	A1 Journal article-refereed

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title = "cis-Diazido[bis(diphenylphosphino)methane-κ2P,P']ruthenium(II) dichloromethane 0.42-solvate",

abstract = "The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis(diphenylphosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium molecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.",

author = "L. Russo and Kalle N{\"a}ttinen and V. Vertlib and J. Rodrigues and Kalle Rissanen",

year = "2006",

doi = "10.1107/S160053680602900X",

language = "English",

volume = "62",

pages = "m2052--m2053",

journal = "Acta Crystallographica Section E: Crystallographic Communications",

issn = "2056-9890",

publisher = "Elsevier",

number = "9",

}

TY - JOUR

T1 - cis-Diazido[bis(diphenylphosphino)methane-κ2P,P']ruthenium(II) dichloromethane 0.42-solvate

AU - Russo, L.

AU - Nättinen, Kalle

AU - Vertlib, V.

AU - Rodrigues, J.

AU - Rissanen, Kalle

PY - 2006

Y1 - 2006

N2 - The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis(diphenylphosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium molecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

AB - The title compound, [Ru(N3)2(C25H22P2)2] or cis-[Ru(N3)2(dppm)2] [dppm is bis(diphenylphosphino)methane], was obtained unexpectedly from our attempts to prepare new ruthenium molecular wires using organic bridging ligands. Both the azido ligands show a triple bond adjacent to the metal.

U2 - 10.1107/S160053680602900X

DO - 10.1107/S160053680602900X

M3 - Article

SN - 2056-9890

VL - 62

SP - m2052-m2053

JO - Acta Crystallographica Section E: Crystallographic Communications

JF - Acta Crystallographica Section E: Crystallographic Communications

IS - 9

ER -

cis-Diazido­[bis­(diphenyl­phosphino)methane-κ2P,P']ruthenium(II) dichloro­methane 0.42-solvate

Abstract

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cis-Diazido[bis(diphenylphosphino)methane-κ²P,P']ruthenium(II) dichloromethane 0.42-solvate