Conduction mechanism of the passive film on iron based on contact electric impedance and resistance measurements

Martin Bojinov, Timo Laitinen (Corresponding Author), Kari Mäkelä, Timo Saario

    Research output: Contribution to journalArticleScientificpeer-review

    47 Citations (Scopus)

    Abstract

    The application of a mixed conduction model and a new contact electric impedance (CEI) technique to predict quantitatively the electronic and ionic transport properties of oxide films on iron in a nearly neutral tetraborate solution is discussed. The mixed-conduction model emphasizes the coupling between the ionic defect structure and the electronic conductivity in an anodic film. Conventional electrochemical techniques have not been sufficient to characterize properly the electronic and ionic properties of anodic films on metals. The CEI technique makes it possible to distinguish between processes taking place at different rates within oxide films. Using this technique together with the contact electric resistance technique, we have found that the diffusion coefficient for the electronic conduction in the anodic film on iron is several orders of magnitude higher than that for the ionic transport. This shows that the passive film on iron is predominantly an electronic conductor. The fitting of the experimental results to the mixed conduction model gives a good agreement and thus supports the validity of this model in the present case.
    Original languageEnglish
    Pages (from-to)B243-B250
    Number of pages8
    JournalJournal of the Electrochemical Society
    Volume148
    Issue number6
    DOIs
    Publication statusPublished - 2001
    MoE publication typeA1 Journal article-refereed

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    Electric impedance measurement
    Electric resistance measurement
    Electric contacts
    Iron
    Oxide films
    Defect structures
    Transport properties
    Metals

    Cite this

    @article{c3f7749741fa48068a521eb31a60341e,
    title = "Conduction mechanism of the passive film on iron based on contact electric impedance and resistance measurements",
    abstract = "The application of a mixed conduction model and a new contact electric impedance (CEI) technique to predict quantitatively the electronic and ionic transport properties of oxide films on iron in a nearly neutral tetraborate solution is discussed. The mixed-conduction model emphasizes the coupling between the ionic defect structure and the electronic conductivity in an anodic film. Conventional electrochemical techniques have not been sufficient to characterize properly the electronic and ionic properties of anodic films on metals. The CEI technique makes it possible to distinguish between processes taking place at different rates within oxide films. Using this technique together with the contact electric resistance technique, we have found that the diffusion coefficient for the electronic conduction in the anodic film on iron is several orders of magnitude higher than that for the ionic transport. This shows that the passive film on iron is predominantly an electronic conductor. The fitting of the experimental results to the mixed conduction model gives a good agreement and thus supports the validity of this model in the present case.",
    author = "Martin Bojinov and Timo Laitinen and Kari M{\"a}kel{\"a} and Timo Saario",
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    Conduction mechanism of the passive film on iron based on contact electric impedance and resistance measurements. / Bojinov, Martin; Laitinen, Timo (Corresponding Author); Mäkelä, Kari; Saario, Timo.

    In: Journal of the Electrochemical Society, Vol. 148, No. 6, 2001, p. B243-B250.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Conduction mechanism of the passive film on iron based on contact electric impedance and resistance measurements

    AU - Bojinov, Martin

    AU - Laitinen, Timo

    AU - Mäkelä, Kari

    AU - Saario, Timo

    PY - 2001

    Y1 - 2001

    N2 - The application of a mixed conduction model and a new contact electric impedance (CEI) technique to predict quantitatively the electronic and ionic transport properties of oxide films on iron in a nearly neutral tetraborate solution is discussed. The mixed-conduction model emphasizes the coupling between the ionic defect structure and the electronic conductivity in an anodic film. Conventional electrochemical techniques have not been sufficient to characterize properly the electronic and ionic properties of anodic films on metals. The CEI technique makes it possible to distinguish between processes taking place at different rates within oxide films. Using this technique together with the contact electric resistance technique, we have found that the diffusion coefficient for the electronic conduction in the anodic film on iron is several orders of magnitude higher than that for the ionic transport. This shows that the passive film on iron is predominantly an electronic conductor. The fitting of the experimental results to the mixed conduction model gives a good agreement and thus supports the validity of this model in the present case.

    AB - The application of a mixed conduction model and a new contact electric impedance (CEI) technique to predict quantitatively the electronic and ionic transport properties of oxide films on iron in a nearly neutral tetraborate solution is discussed. The mixed-conduction model emphasizes the coupling between the ionic defect structure and the electronic conductivity in an anodic film. Conventional electrochemical techniques have not been sufficient to characterize properly the electronic and ionic properties of anodic films on metals. The CEI technique makes it possible to distinguish between processes taking place at different rates within oxide films. Using this technique together with the contact electric resistance technique, we have found that the diffusion coefficient for the electronic conduction in the anodic film on iron is several orders of magnitude higher than that for the ionic transport. This shows that the passive film on iron is predominantly an electronic conductor. The fitting of the experimental results to the mixed conduction model gives a good agreement and thus supports the validity of this model in the present case.

    U2 - 10.1149/1.1371976

    DO - 10.1149/1.1371976

    M3 - Article

    VL - 148

    SP - B243-B250

    JO - Journal of the Electrochemical Society

    JF - Journal of the Electrochemical Society

    SN - 0013-4651

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    ER -