Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant

Martta Asikainen; Olli Jauhiainen; Olli Aaltonen; Ali Harlin

doi:10.1039/c3gc41224e

Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant

Martta Asikainen^*
, Olli Jauhiainen
, Olli Aaltonen
, Ali Harlin

^*Corresponding author for this work

VTT (former employee or external)

Research output: Contribution to journal › Article › Scientific › peer-review

32 Citations (Scopus)

Abstract

The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.

Original language	English
Pages (from-to)	3230-3235
Journal	Green Chemistry
Volume	15
Issue number	11
DOIs	https://doi.org/10.1039/c3gc41224e
Publication status	Published - 2013
MoE publication type	A1 Journal article-refereed

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title = "Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant",

abstract = "The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.",

author = "Martta Asikainen and Olli Jauhiainen and Olli Aaltonen and Ali Harlin",

year = "2013",

doi = "10.1039/c3gc41224e",

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AU - Asikainen, Martta

AU - Jauhiainen, Olli

AU - Aaltonen, Olli

AU - Harlin, Ali

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Y1 - 2013

N2 - The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.

AB - The dehydrogenation of γ-terpinene was studied under catalyst- and solvent-free reaction conditions using air as an oxidant. The dehydrogenation affords p-cymene in good yields in a continuous flow reaction setup. The initial optimization of the reaction parameters showed that the dehydrogenation is highly dependent on the vapour/liquid phase equilibrium and the availability of oxygen in the vapour phase.

U2 - 10.1039/c3gc41224e

DO - 10.1039/c3gc41224e

M3 - Article

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VL - 15

SP - 3230

EP - 3235

JO - Green Chemistry

JF - Green Chemistry

IS - 11

ER -

Continuous catalyst-free aromatization of γ-terpinene using air as an oxidant

Abstract

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