Coprecipitation of Ni with CaCO3: An experimental study

Torbjörn Carlsson, Hannu Aalto

Research output: Book/ReportReport

Abstract

The performance assessment of repositories for spent nuclear fuel need, among other things, data describing the solubilities of radionuclides in the near field and far field. The solubility limits are often used in order to estimate the maximum concentrations of radionuclides during their possible transport to the biosphere. The solubilities used are mostly the individual solubilities for pure solids of the actual radionuclides. This way of using solubility limits represents a conservative performance assessment where the estimated nuclide concentrations are unrealistically high. This is acceptable from a performance assessment point of view but very unsatisfactory for an optimal design of the repository. In order to make the assessment more realistic, coprecipitation and solid solution formation should be taken into account. Only solids which are, in geological terms, formed in fast reactions need to be considered, which in practice restricts the number of radionuclide scavengers to calcite and iron(III)oxihydroxide. This work focuses on calcite coprecipitation only. This report gives a short introduction to the theory of coprecipitation. The report also presents some preliminary experimental work on the coprecipitation of trace concentrations of nickel with calcite under anoxic conditions. The experimental conditions were chosen such that no individual Ni solids would form; i.e. the only way for Ni to precipitate was via coprecipitation. Calculated mole fractions of NiCO3 in the coprecipitate formed, and estimates of the conditional solubility constants for the NiCO3 are also presented.
Original languageEnglish
Place of PublicationEspoo
PublisherVTT Technical Research Centre of Finland
Number of pages26
ISBN (Print)951-38-4866-3
Publication statusPublished - 1995
MoE publication typeNot Eligible

Publication series

SeriesVTT Tiedotteita - Meddelanden - Research Notes
Number1712
ISSN1235-0605

Fingerprint

solubility
experimental study
radionuclide
performance assessment
calcite
repository
scavenger
solid solution
anoxic conditions
biosphere
nickel
iron

Keywords

  • nuclear power plants
  • radioactive waste storage
  • nuclear fuels
  • solubility
  • radioactive isotopes
  • environmental protection
  • solid solutions
  • nickel
  • calcite
  • experimentation

Cite this

Carlsson, T., & Aalto, H. (1995). Coprecipitation of Ni with CaCO3: An experimental study. Espoo: VTT Technical Research Centre of Finland. VTT Tiedotteita - Meddelanden - Research Notes, No. 1712
Carlsson, Torbjörn ; Aalto, Hannu. / Coprecipitation of Ni with CaCO3 : An experimental study. Espoo : VTT Technical Research Centre of Finland, 1995. 26 p. (VTT Tiedotteita - Meddelanden - Research Notes; No. 1712).
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Carlsson, T & Aalto, H 1995, Coprecipitation of Ni with CaCO3: An experimental study. VTT Tiedotteita - Meddelanden - Research Notes, no. 1712, VTT Technical Research Centre of Finland, Espoo.

Coprecipitation of Ni with CaCO3 : An experimental study. / Carlsson, Torbjörn; Aalto, Hannu.

Espoo : VTT Technical Research Centre of Finland, 1995. 26 p. (VTT Tiedotteita - Meddelanden - Research Notes; No. 1712).

Research output: Book/ReportReport

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T1 - Coprecipitation of Ni with CaCO3

T2 - An experimental study

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AU - Aalto, Hannu

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Carlsson T, Aalto H. Coprecipitation of Ni with CaCO3: An experimental study. Espoo: VTT Technical Research Centre of Finland, 1995. 26 p. (VTT Tiedotteita - Meddelanden - Research Notes; No. 1712).