Crosslinkable poly(lactic acid)-based materials: Biomass-derived solution for barrier coatings

Tuomas Mehtiö, Adina Anghelescu-Hakala, Jonas Hartman, Vesa Kunnari, Ali Harlin

Research output: Contribution to journalArticleScientificpeer-review

4 Citations (Scopus)

Abstract

The demand for biobased barrier packaging alternatives is constantly growing. Poly(lactic acid) (PLA)-based polymers are one of the most extensively studied biomass-derived synthetic polymers; however, they typically lack water-barrier properties. We synthesized a copolymer of d,l-lactic acid, 1,4-butanediol, and itaconic acid [poly(d,l-lactic acid-1,4-butanediol-itaconic acid) (PLABDIA)] via bulk polycondensation. The radical crosslinking reactions of the synthesized polymer were investigated with bulk crosslinking trials to find a formulation that was suitable for a rapidly crosslinkable barrier coating. The crosslinking efficiency was tested with methacrylate and acrylate crosslinkers together with peroxide radical initiators. Poly(ethylene glycol) diacrylate (number-average molecular weight = 250 g/mol) together with dilauroyl peroxide proved to be the best crosslinker-initiator combination. An aqueous dispersion of PLABDIA was prepared with a thermomechanical method and applied to commercial boxboard on a pilot-scale line coater. With a coating weight of 10 g/m2, a water vapor transmission rate of 22.8 g/m2d was achieved, and this coating outperformed commercial extruded PLA coatings. The samples also showed very good grease resistance and would, therefore, be a good solution for the packaging of dry and fatty goods.
Original languageEnglish
Article number44326
JournalJournal of Applied Polymer Science
Volume134
Issue number1
DOIs
Publication statusPublished - 2017
MoE publication typeA1 Journal article-refereed

Fingerprint

Lactic acid
Biomass
Crosslinking
Coatings
Polymers
Peroxides
Acids
Packaging
Methacrylates
Steam
Lubricating greases
Polycondensation
Water vapor
Polyethylene glycols
Lactic Acid
Copolymers
Molecular weight
poly(lactic acid)
Water
1,4-butanediol

Keywords

  • biopolymers and renewable polymers
  • coatings
  • packaging
  • polycondensation
  • polyesters

Cite this

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title = "Crosslinkable poly(lactic acid)-based materials: Biomass-derived solution for barrier coatings",
abstract = "The demand for biobased barrier packaging alternatives is constantly growing. Poly(lactic acid) (PLA)-based polymers are one of the most extensively studied biomass-derived synthetic polymers; however, they typically lack water-barrier properties. We synthesized a copolymer of d,l-lactic acid, 1,4-butanediol, and itaconic acid [poly(d,l-lactic acid-1,4-butanediol-itaconic acid) (PLABDIA)] via bulk polycondensation. The radical crosslinking reactions of the synthesized polymer were investigated with bulk crosslinking trials to find a formulation that was suitable for a rapidly crosslinkable barrier coating. The crosslinking efficiency was tested with methacrylate and acrylate crosslinkers together with peroxide radical initiators. Poly(ethylene glycol) diacrylate (number-average molecular weight = 250 g/mol) together with dilauroyl peroxide proved to be the best crosslinker-initiator combination. An aqueous dispersion of PLABDIA was prepared with a thermomechanical method and applied to commercial boxboard on a pilot-scale line coater. With a coating weight of 10 g/m2, a water vapor transmission rate of 22.8 g/m2d was achieved, and this coating outperformed commercial extruded PLA coatings. The samples also showed very good grease resistance and would, therefore, be a good solution for the packaging of dry and fatty goods.",
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Crosslinkable poly(lactic acid)-based materials : Biomass-derived solution for barrier coatings. / Mehtiö, Tuomas; Anghelescu-Hakala, Adina; Hartman, Jonas; Kunnari, Vesa; Harlin, Ali.

In: Journal of Applied Polymer Science, Vol. 134, No. 1, 44326, 2017.

Research output: Contribution to journalArticleScientificpeer-review

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T2 - Biomass-derived solution for barrier coatings

AU - Mehtiö, Tuomas

AU - Anghelescu-Hakala, Adina

AU - Hartman, Jonas

AU - Kunnari, Vesa

AU - Harlin, Ali

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