Abstract
The concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Pb, Sb, Ti, V and Zn in the soft tissues of the mussels and in different fractions of the shells were determined by wet digestion and atomic absorption spectrometry.
Mussel samples were collected at twelve sampling sites at measured distances from the main contamination sources: the local titanium oxide industry and the river Kokemäenjoki. At the same sites, mussels from another area maintained in cages were exposed to the heavy metal uptake for about 2.5 months.
Both the local and caged mussels were analyzed.
The data, consisting of the concentrations of 13 elements, the percentages of shell deformities and the distances from the sources of pollution, were studied by SIMCA and partial least squares (PLS) methods. The shell deformities and the distances from the two pollution sources were treated as dependent variables in PLS. Calculations were made using the data of different fractions alone and of many fractions together. The PLS predictions for the distances were used to estimate the size of the polluted area. Up to 20–40 kilometers from the pollution sources the prediction models fitted well to the measured distances.
The study showed that the elemental variables Fe, Ti and V were most strongly related to the titanium oxide industry and Al, Co, Hg and Mn to the river Kokemäenjoki.
Original language | English |
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Pages (from-to) | 163-170 |
Journal | Chemometrics and Intelligent Laboratory Systems |
Volume | 7 |
Issue number | 1-2 |
DOIs | |
Publication status | Published - 1989 |
MoE publication type | A1 Journal article-refereed |
Event | First Scandinavian Symposium on Chemometrics - Lappeenranta, Finland Duration: 6 Oct 1989 → 8 Oct 1989 |
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Data analysis of heavy metal pollution in the sea by using principal component analysis and partial least squares regression. / Piepponen, Sulo; Lindström, Reijo.
In: Chemometrics and Intelligent Laboratory Systems, Vol. 7, No. 1-2, 1989, p. 163-170.Research output: Contribution to journal › Article › Scientific › peer-review
TY - JOUR
T1 - Data analysis of heavy metal pollution in the sea by using principal component analysis and partial least squares regression
AU - Piepponen, Sulo
AU - Lindström, Reijo
PY - 1989
Y1 - 1989
N2 - Environmental heavy metal pollution in the coastal waters of the Bothnian Sea near the city of Pori was monitored by observations of mussels (Mytilus edulis L.). The concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Pb, Sb, Ti, V and Zn in the soft tissues of the mussels and in different fractions of the shells were determined by wet digestion and atomic absorption spectrometry.Mussel samples were collected at twelve sampling sites at measured distances from the main contamination sources: the local titanium oxide industry and the river Kokemäenjoki. At the same sites, mussels from another area maintained in cages were exposed to the heavy metal uptake for about 2.5 months. Both the local and caged mussels were analyzed.The data, consisting of the concentrations of 13 elements, the percentages of shell deformities and the distances from the sources of pollution, were studied by SIMCA and partial least squares (PLS) methods. The shell deformities and the distances from the two pollution sources were treated as dependent variables in PLS. Calculations were made using the data of different fractions alone and of many fractions together. The PLS predictions for the distances were used to estimate the size of the polluted area. Up to 20–40 kilometers from the pollution sources the prediction models fitted well to the measured distances. The study showed that the elemental variables Fe, Ti and V were most strongly related to the titanium oxide industry and Al, Co, Hg and Mn to the river Kokemäenjoki.
AB - Environmental heavy metal pollution in the coastal waters of the Bothnian Sea near the city of Pori was monitored by observations of mussels (Mytilus edulis L.). The concentrations of Al, As, Cd, Co, Cr, Cu, Fe, Hg, Mn, Pb, Sb, Ti, V and Zn in the soft tissues of the mussels and in different fractions of the shells were determined by wet digestion and atomic absorption spectrometry.Mussel samples were collected at twelve sampling sites at measured distances from the main contamination sources: the local titanium oxide industry and the river Kokemäenjoki. At the same sites, mussels from another area maintained in cages were exposed to the heavy metal uptake for about 2.5 months. Both the local and caged mussels were analyzed.The data, consisting of the concentrations of 13 elements, the percentages of shell deformities and the distances from the sources of pollution, were studied by SIMCA and partial least squares (PLS) methods. The shell deformities and the distances from the two pollution sources were treated as dependent variables in PLS. Calculations were made using the data of different fractions alone and of many fractions together. The PLS predictions for the distances were used to estimate the size of the polluted area. Up to 20–40 kilometers from the pollution sources the prediction models fitted well to the measured distances. The study showed that the elemental variables Fe, Ti and V were most strongly related to the titanium oxide industry and Al, Co, Hg and Mn to the river Kokemäenjoki.
U2 - 10.1016/0169-7439(89)80120-0
DO - 10.1016/0169-7439(89)80120-0
M3 - Article
VL - 7
SP - 163
EP - 170
JO - Chemometrics and Intelligent Laboratory Systems
JF - Chemometrics and Intelligent Laboratory Systems
SN - 0169-7439
IS - 1-2
ER -