Surface samples from a full poloidal set of divertor tiles exposed in JET through operations 2010-2012 with ITER-like wall have been investigated using SEM, SIMS, ICP-AES analysis and micro beam nuclear reaction analysis (µ-NRA). Deposition of Be and retention of D is microscopically inhomogeneous. With careful overlaying of µ-NRA elemental maps with SEM images, it is possible to separate surface roughness effects from depth profiles at microscopically flat surface regions, without pits. With (3He, p) µ-NRA at 3-5 MeV beam energy the accessible depth for D analysis in W is about 9 µm, sufficient to access the W/Mo and Mo/W interfaces in the coatings and beyond, while for Be in W it is about 6 µm. In these conditions, at all plasma wetted surfaces, D was found throughout the whole accessible depth at concentrations in the range 0.2-0.7 at% in W. Deuterium was found to be preferentially trapped at the W/Mo and Mo/W interfaces. Comparison is made with SIMS profiling, which also shows significant D trapping at the W/Mo interface. Mixing of Be and W occurs mainly in deposited layers.
- ion beam analysis
- materials migration