Depth profiles in coated paper: Experimental and simulated FT-IR photoacoustic difference magnitude spectra

M. W.C. Wahls, Eija Kenttä, J. C. Leyte

Research output: Contribution to journalArticleScientificpeer-review

17 Citations (Scopus)

Abstract

Experimental photoacoustic (PA) magnitude spectra of a coated paper and the uncoated basepaper are presented. The normalized and scaled PA magnitude spectra are used to calculate difference magnitude spectra. It was decided to scale all PA magnitude spectra to (low) equal intensity at the approximately optically thin spectral range before subtraction. Then no infrared (IR) bands of identical band shape and height (as needed for common difference spectroscopy) in either PA magnitude spectrum are needed. Contributions of the two individual layers to the IR-PA magnitude spectrum of the coated paper are separated in the difference spectrum by their sign. An increasing relative contribution of the coating layer with an increasing phase modulation frequency is found. On decreasing the thermal length to a value near the coating thickness, the difference spectra increasingly show positive coating bands and negative bulk signals. The extension of the Rosencwaig-Gersho theory to a double-layered system introduced by N. C. Fernelius applied to synthetic spectra confirms the experimental observation. It is found that photoacoustic difference spectroscopy may provide quantitative depth-resolved spectral information due to the presented scaling procedure, and photoacoustic difference magnitude spectra of any polymeric laminate may therefore be calculated.

Original languageEnglish
Pages (from-to)214-220
JournalApplied Spectroscopy
Volume54
Issue number2
DOIs
Publication statusPublished - 1 Jan 2000
MoE publication typeA1 Journal article-refereed

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Photoacoustic effect
Infrared radiation
profiles
Coatings
Spectroscopy
coatings
Phase modulation
Laminates
subtraction
phase modulation
spectroscopy
laminates
scaling

Cite this

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abstract = "Experimental photoacoustic (PA) magnitude spectra of a coated paper and the uncoated basepaper are presented. The normalized and scaled PA magnitude spectra are used to calculate difference magnitude spectra. It was decided to scale all PA magnitude spectra to (low) equal intensity at the approximately optically thin spectral range before subtraction. Then no infrared (IR) bands of identical band shape and height (as needed for common difference spectroscopy) in either PA magnitude spectrum are needed. Contributions of the two individual layers to the IR-PA magnitude spectrum of the coated paper are separated in the difference spectrum by their sign. An increasing relative contribution of the coating layer with an increasing phase modulation frequency is found. On decreasing the thermal length to a value near the coating thickness, the difference spectra increasingly show positive coating bands and negative bulk signals. The extension of the Rosencwaig-Gersho theory to a double-layered system introduced by N. C. Fernelius applied to synthetic spectra confirms the experimental observation. It is found that photoacoustic difference spectroscopy may provide quantitative depth-resolved spectral information due to the presented scaling procedure, and photoacoustic difference magnitude spectra of any polymeric laminate may therefore be calculated.",
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Depth profiles in coated paper : Experimental and simulated FT-IR photoacoustic difference magnitude spectra. / Wahls, M. W.C.; Kenttä, Eija; Leyte, J. C.

In: Applied Spectroscopy, Vol. 54, No. 2, 01.01.2000, p. 214-220.

Research output: Contribution to journalArticleScientificpeer-review

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