Determination of NH3 in pyrolysis gases by ammonia selective electrode

Jouni Hämäläinen, Jouni Tummavuori, Martti Aho

    Research output: Contribution to journalArticleScientificpeer-review

    7 Citations (Scopus)

    Abstract

    The suitability of ion-selective electrode for the determination of ammonia in pyrolysis gases of fossil fuels was studied. The ammonia was absorbed into acidic solution and two kinds of determination methods were carried out. The ammonia was either measured directly from the acid solution, or ammonia was first released into the gas phase and then determined (air gap method) by the ammonia selective electrode. The electrode functioned well in both cases, but the linear calibration range was rather narrow, slightly more than one tenfold. The quantitative detection limit in the water phase was 5 × 10−6M (0.085 ppm) NH3 and in gas phase operation solutions above 5 × 10−4M (8.5 ppm) NH3 it was possible to measure quantitatively. The applications were carried out with Finnish energy peat samples and a coal sample.

    Original languageEnglish
    Pages (from-to)1575 - 1581
    Number of pages7
    JournalTalanta
    Volume40
    Issue number10
    DOIs
    Publication statusPublished - 1993
    MoE publication typeA1 Journal article-refereed

    Keywords

    • ammonia
    • determination
    • pyrolysis products
    • gases
    • ion-selective electrodes

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