Determination of the degree of substitution of acetylated starch by hydrolysis, 1H NMR and TGA/IR

Matti Elomaa (Corresponding Author), Tomas Asplund, Pasi Soininen, Reino Laatikainen, Soili Peltonen, Sari Hyvärinen, Arto Urtti

    Research output: Contribution to journalArticleScientificpeer-review

    144 Citations (Scopus)

    Abstract

    The suitability of TGA/IR method for the analysis of the degree of substitution (DS) of acetylated starch (SA) was assessed. Ten standard samples were analysed for their DS by hydrolysis method and, those of the standards which could be properly dissolved, also by 1H NMR. NMR analysis shows as well that the standards had other structural differences than DS. By TGA using derivatives of thermograms (DTG) it was possible to predict the DS with percentual coefficient of determination of 98. Somewhat more accurate results (R2=98.7) were received when the evolving acetic acid was analysed by IR. The result is very good because it is at the same precision level as the results of the hydrolysis and 1H NMR methods.
    Original languageEnglish
    Pages (from-to)261 - 267
    Number of pages7
    JournalCarbohydrate Polymers
    Volume57
    Issue number3
    DOIs
    Publication statusPublished - 2004
    MoE publication typeA1 Journal article-refereed

    Fingerprint

    Starch
    Hydrolysis
    Substitution reactions
    Nuclear magnetic resonance
    Acetic acid
    Acetic Acid
    Derivatives

    Keywords

    • acetylated starch; degree of substitution; TGA/IR; NMR
    • biopolymers

    Cite this

    Elomaa, Matti ; Asplund, Tomas ; Soininen, Pasi ; Laatikainen, Reino ; Peltonen, Soili ; Hyvärinen, Sari ; Urtti, Arto. / Determination of the degree of substitution of acetylated starch by hydrolysis, 1H NMR and TGA/IR. In: Carbohydrate Polymers. 2004 ; Vol. 57, No. 3. pp. 261 - 267.
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    Determination of the degree of substitution of acetylated starch by hydrolysis, 1H NMR and TGA/IR. / Elomaa, Matti (Corresponding Author); Asplund, Tomas; Soininen, Pasi; Laatikainen, Reino; Peltonen, Soili; Hyvärinen, Sari; Urtti, Arto.

    In: Carbohydrate Polymers, Vol. 57, No. 3, 2004, p. 261 - 267.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Determination of the degree of substitution of acetylated starch by hydrolysis, 1H NMR and TGA/IR

    AU - Elomaa, Matti

    AU - Asplund, Tomas

    AU - Soininen, Pasi

    AU - Laatikainen, Reino

    AU - Peltonen, Soili

    AU - Hyvärinen, Sari

    AU - Urtti, Arto

    PY - 2004

    Y1 - 2004

    N2 - The suitability of TGA/IR method for the analysis of the degree of substitution (DS) of acetylated starch (SA) was assessed. Ten standard samples were analysed for their DS by hydrolysis method and, those of the standards which could be properly dissolved, also by 1H NMR. NMR analysis shows as well that the standards had other structural differences than DS. By TGA using derivatives of thermograms (DTG) it was possible to predict the DS with percentual coefficient of determination of 98. Somewhat more accurate results (R2=98.7) were received when the evolving acetic acid was analysed by IR. The result is very good because it is at the same precision level as the results of the hydrolysis and 1H NMR methods.

    AB - The suitability of TGA/IR method for the analysis of the degree of substitution (DS) of acetylated starch (SA) was assessed. Ten standard samples were analysed for their DS by hydrolysis method and, those of the standards which could be properly dissolved, also by 1H NMR. NMR analysis shows as well that the standards had other structural differences than DS. By TGA using derivatives of thermograms (DTG) it was possible to predict the DS with percentual coefficient of determination of 98. Somewhat more accurate results (R2=98.7) were received when the evolving acetic acid was analysed by IR. The result is very good because it is at the same precision level as the results of the hydrolysis and 1H NMR methods.

    KW - acetylated starch; degree of substitution; TGA/IR; NMR

    KW - biopolymers

    U2 - 10.1016/j.carbpol.2004.05.003

    DO - 10.1016/j.carbpol.2004.05.003

    M3 - Article

    VL - 57

    SP - 261

    EP - 267

    JO - Carbohydrate Polymers

    JF - Carbohydrate Polymers

    SN - 0144-8617

    IS - 3

    ER -