Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method

Vitali Trunov, Valeri Kudryashev, A. Bulkin, V. Ulyanov, A. Loshmanov, Antero Tiitta, Olli Antson, Pekka Hiismäki, Hannu Mutka, Heikki Pöyry

Research output: Contribution to journalArticleScientificpeer-review

9 Citations (Scopus)

Abstract

Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.

The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

Original languageEnglish
Pages (from-to)95 - 97
Number of pages3
JournalSolid State Communications
Volume59
Issue number2
DOIs
Publication statusPublished - 1986
MoE publication typeNot Eligible

Fingerprint

Powders
Neutrons
Diffraction
neutrons
diffraction
Atoms
neutron activation analysis
Neutron activation analysis
optical measurement
YAG lasers
Hydrogen
hydrogen atoms
contamination
Contamination
Single crystals
harmonics
X rays
Lasers
single crystals
atoms

Cite this

Trunov, V., Kudryashev, V., Bulkin, A., Ulyanov, V., Loshmanov, A., Tiitta, A., ... Pöyry, H. (1986). Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. Solid State Communications, 59(2), 95 - 97. https://doi.org/10.1016/0038-1098(86)90293-0
Trunov, Vitali ; Kudryashev, Valeri ; Bulkin, A. ; Ulyanov, V. ; Loshmanov, A. ; Tiitta, Antero ; Antson, Olli ; Hiismäki, Pekka ; Mutka, Hannu ; Pöyry, Heikki. / Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. In: Solid State Communications. 1986 ; Vol. 59, No. 2. pp. 95 - 97.
@article{4661b89b5f014572872498bc4feea06a,
title = "Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method",
abstract = "Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.",
author = "Vitali Trunov and Valeri Kudryashev and A. Bulkin and V. Ulyanov and A. Loshmanov and Antero Tiitta and Olli Antson and Pekka Hiism{\"a}ki and Hannu Mutka and Heikki P{\"o}yry",
year = "1986",
doi = "10.1016/0038-1098(86)90293-0",
language = "English",
volume = "59",
pages = "95 -- 97",
journal = "Solid State Communications",
issn = "0038-1098",
publisher = "Elsevier",
number = "2",

}

Trunov, V, Kudryashev, V, Bulkin, A, Ulyanov, V, Loshmanov, A, Tiitta, A, Antson, O, Hiismäki, P, Mutka, H & Pöyry, H 1986, 'Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method', Solid State Communications, vol. 59, no. 2, pp. 95 - 97. https://doi.org/10.1016/0038-1098(86)90293-0

Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. / Trunov, Vitali; Kudryashev, Valeri; Bulkin, A.; Ulyanov, V.; Loshmanov, A.; Tiitta, Antero; Antson, Olli; Hiismäki, Pekka; Mutka, Hannu; Pöyry, Heikki.

In: Solid State Communications, Vol. 59, No. 2, 1986, p. 95 - 97.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method

AU - Trunov, Vitali

AU - Kudryashev, Valeri

AU - Bulkin, A.

AU - Ulyanov, V.

AU - Loshmanov, A.

AU - Tiitta, Antero

AU - Antson, Olli

AU - Hiismäki, Pekka

AU - Mutka, Hannu

AU - Pöyry, Heikki

PY - 1986

Y1 - 1986

N2 - Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

AB - Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

U2 - 10.1016/0038-1098(86)90293-0

DO - 10.1016/0038-1098(86)90293-0

M3 - Article

VL - 59

SP - 95

EP - 97

JO - Solid State Communications

JF - Solid State Communications

SN - 0038-1098

IS - 2

ER -