Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method

Vitali Trunov, Valeri Kudryashev, A. Bulkin, V. Ulyanov, A. Loshmanov, Antero Tiitta, Olli Antson, Pekka Hiismäki, Hannu Mutka, Heikki Pöyry

    Research output: Contribution to journalArticleScientificpeer-review

    9 Citations (Scopus)

    Abstract

    Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.

    The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

    Original languageEnglish
    Pages (from-to)95 - 97
    Number of pages3
    JournalSolid State Communications
    Volume59
    Issue number2
    DOIs
    Publication statusPublished - 1986
    MoE publication typeNot Eligible

    Fingerprint

    Powders
    Neutrons
    Diffraction
    neutrons
    diffraction
    Atoms
    neutron activation analysis
    Neutron activation analysis
    optical measurement
    YAG lasers
    Hydrogen
    hydrogen atoms
    contamination
    Contamination
    Single crystals
    harmonics
    X rays
    Lasers
    single crystals
    atoms

    Cite this

    Trunov, V., Kudryashev, V., Bulkin, A., Ulyanov, V., Loshmanov, A., Tiitta, A., ... Pöyry, H. (1986). Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. Solid State Communications, 59(2), 95 - 97. https://doi.org/10.1016/0038-1098(86)90293-0
    Trunov, Vitali ; Kudryashev, Valeri ; Bulkin, A. ; Ulyanov, V. ; Loshmanov, A. ; Tiitta, Antero ; Antson, Olli ; Hiismäki, Pekka ; Mutka, Hannu ; Pöyry, Heikki. / Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. In: Solid State Communications. 1986 ; Vol. 59, No. 2. pp. 95 - 97.
    @article{4661b89b5f014572872498bc4feea06a,
    title = "Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method",
    abstract = "Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.",
    author = "Vitali Trunov and Valeri Kudryashev and A. Bulkin and V. Ulyanov and A. Loshmanov and Antero Tiitta and Olli Antson and Pekka Hiism{\"a}ki and Hannu Mutka and Heikki P{\"o}yry",
    year = "1986",
    doi = "10.1016/0038-1098(86)90293-0",
    language = "English",
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    journal = "Solid State Communications",
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    Trunov, V, Kudryashev, V, Bulkin, A, Ulyanov, V, Loshmanov, A, Tiitta, A, Antson, O, Hiismäki, P, Mutka, H & Pöyry, H 1986, 'Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method', Solid State Communications, vol. 59, no. 2, pp. 95 - 97. https://doi.org/10.1016/0038-1098(86)90293-0

    Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method. / Trunov, Vitali; Kudryashev, Valeri; Bulkin, A.; Ulyanov, V.; Loshmanov, A.; Tiitta, Antero; Antson, Olli; Hiismäki, Pekka; Mutka, Hannu; Pöyry, Heikki.

    In: Solid State Communications, Vol. 59, No. 2, 1986, p. 95 - 97.

    Research output: Contribution to journalArticleScientificpeer-review

    TY - JOUR

    T1 - Determination of the structure of Y(HCOO)3 by the neutron time-of-flight diffraction method

    AU - Trunov, Vitali

    AU - Kudryashev, Valeri

    AU - Bulkin, A.

    AU - Ulyanov, V.

    AU - Loshmanov, A.

    AU - Tiitta, Antero

    AU - Antson, Olli

    AU - Hiismäki, Pekka

    AU - Mutka, Hannu

    AU - Pöyry, Heikki

    PY - 1986

    Y1 - 1986

    N2 - Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

    AB - Optical measurements have shown that the two types of Y(HCOO)3, i.e. the powder type and the recrystallized type, have notable differences in second harmonic properties as measured with a Nd:YAG laser. We performed a neutron time-of-flight measurement on the powder type in order to explain the optical behaviour by structural differences.The results show that the position parameters of the heavy atoms of the powder type are the same as those given by a single crystal X-ray study for the recrystallized type. Moreover the position parameters of the hydrogen atoms were determined for the first time. The effect of contamination determined by neutron activation analysis is also shortly discussed.

    U2 - 10.1016/0038-1098(86)90293-0

    DO - 10.1016/0038-1098(86)90293-0

    M3 - Article

    VL - 59

    SP - 95

    EP - 97

    JO - Solid State Communications

    JF - Solid State Communications

    SN - 0038-1098

    IS - 2

    ER -