Development of Continuously Operating Two-Dimensional Thermal Field-Flow Fractionation Equipment

Pertti Vastamäki, Matti Jussila, Marja-Liisa Riekkola (Corresponding Author)

Research output: Contribution to journalArticleScientificpeer-review

6 Citations (Scopus)

Abstract

A new type of the thermal field-flow fractionation apparatus designed and constructed in the Laboratory of Analytical Chemistry provides continuous fractionation of polymers according to their molecular masses. The principle is to separate sample components into filaments from the continuous sample flow in a disk-shaped channel and to collect a sample species at the circumference of the channel. The upper wall of the channel is stationary, and the lower one rotates slowly. The method is based on a two-dimensional fractionation mechanism and demonstrates the collection of 2 polystyrene samples in a cyclohexane carrier. The method also provides a gentle fractionation environment for high polymers with low shear forces, flexible run conditions, and numerous industrial applications from special products to process quality control. The construction procedure of the complete apparatus is described with technical details.
Original languageEnglish
Pages (from-to)2535-2545
Number of pages11
JournalSeparation Science and Technology
Volume36
Issue number11
DOIs
Publication statusPublished - 2001
MoE publication typeA1 Journal article-refereed

Keywords

  • field-flow fractionation
  • continuous fractionation
  • two-dimensional separation
  • thermal gradient
  • polystyrene
  • cyclohexane
  • tetrahydrofuran

Fingerprint Dive into the research topics of 'Development of Continuously Operating Two-Dimensional Thermal Field-Flow Fractionation Equipment'. Together they form a unique fingerprint.

  • Cite this