Development of on-line measurement techniques for siloxanes and other trace compounds in biogas

Mona Arnold (Corresponding Author), Tuula Kajolinna

Research output: Contribution to journalArticleScientificpeer-review

53 Citations (Scopus)

Abstract

This paper focuses on the development of an on-line measurement method for siloxanes and other biogas trace compounds impeding the energy utilisation of biogas, as well as the main gas components, methane and carbon dioxide. The method is based on gas chromatography and FT-IR-analysis. The level of siloxane, hydrogen sulphide and halogens in biogas generated in a number of landfills and digesters in Finland is also presented and factors affecting the concentrations discussed. Generally, the level of biogas trace compounds hampering electricity production was lower than those measured at comparable sites in Central Europe and the US. Moreover, the paper discusses the significance of on-line monitoring of siloxane in connection to biogas-to-electricity applications and points out with activated carbon as an example the benefits of on-line siloxane measurement in the control of siloxane removal technology.
Original languageEnglish
Pages (from-to)1011-1017
Number of pages7
JournalWaste Management
Volume30
Issue number6
DOIs
Publication statusPublished - 2010
MoE publication typeA1 Journal article-refereed

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biogas
electricity
measurement method
halogen
hydrogen sulfide
activated carbon
landfill
gas chromatography
carbon dioxide
methane
monitoring
gas

Cite this

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title = "Development of on-line measurement techniques for siloxanes and other trace compounds in biogas",
abstract = "This paper focuses on the development of an on-line measurement method for siloxanes and other biogas trace compounds impeding the energy utilisation of biogas, as well as the main gas components, methane and carbon dioxide. The method is based on gas chromatography and FT-IR-analysis. The level of siloxane, hydrogen sulphide and halogens in biogas generated in a number of landfills and digesters in Finland is also presented and factors affecting the concentrations discussed. Generally, the level of biogas trace compounds hampering electricity production was lower than those measured at comparable sites in Central Europe and the US. Moreover, the paper discusses the significance of on-line monitoring of siloxane in connection to biogas-to-electricity applications and points out with activated carbon as an example the benefits of on-line siloxane measurement in the control of siloxane removal technology.",
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Development of on-line measurement techniques for siloxanes and other trace compounds in biogas. / Arnold, Mona (Corresponding Author); Kajolinna, Tuula.

In: Waste Management, Vol. 30, No. 6, 2010, p. 1011-1017.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Development of on-line measurement techniques for siloxanes and other trace compounds in biogas

AU - Arnold, Mona

AU - Kajolinna, Tuula

PY - 2010

Y1 - 2010

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AB - This paper focuses on the development of an on-line measurement method for siloxanes and other biogas trace compounds impeding the energy utilisation of biogas, as well as the main gas components, methane and carbon dioxide. The method is based on gas chromatography and FT-IR-analysis. The level of siloxane, hydrogen sulphide and halogens in biogas generated in a number of landfills and digesters in Finland is also presented and factors affecting the concentrations discussed. Generally, the level of biogas trace compounds hampering electricity production was lower than those measured at comparable sites in Central Europe and the US. Moreover, the paper discusses the significance of on-line monitoring of siloxane in connection to biogas-to-electricity applications and points out with activated carbon as an example the benefits of on-line siloxane measurement in the control of siloxane removal technology.

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