Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying

Luis B. Modesto-López (Corresponding Author), Mirella Miettinen, Tiina Torvela, Anna Lähde, Jorma Jokiniemi

Research output: Contribution to journalArticleScientificpeer-review

10 Citations (Scopus)

Abstract

In this work, suspensions of two types of graphene nanomaterials - graphene nanoflowers (GNFs) and multilayer graphene (MLG) flakes - were ultrasonically sprayed into micrometer-sized droplets to directly form films on glass and methacrylic acid copolymer (MA)-modified glass substrates. Poly(vinylidene fluoride) (PVDF) was added to the suspensions to enhance the structural robustness of films. While PVDF enhanced nanomaterial binding, the MA coating boosted nanomaterial adhesion to the substrate. The films' morphology, adhesion, and electrical properties were investigated. MLG flakes produced highly irregular films, conversely GNFs formed thinner and more uniform layers. In the case of MLG flakes, films on MA-coated glass showed lower resistances compared to those on glass. GNF suspensions sprayed on MA-coated glass resulted in graphene nanostructures embedded in a predominantly dielectric polymer matrix. Thus, in the case of GNFs, films on glass exhibited lower resistances compared to those on MA-coated glass. The approach described herein can be readily extended to create films of other graphene-based materials on a variety of substrates.
Original languageEnglish
Pages (from-to)45-52
JournalThin Solid Films
Volume578
DOIs
Publication statusPublished - 2015
MoE publication typeA1 Journal article-refereed

Fingerprint

Graphite
spraying
Spraying
Nanostructured materials
Graphene
graphene
Polymers
ultrasonics
Ultrasonics
Glass
Nanoflowers
glass
polymers
copolymers
Copolymers
flakes
acids
Acids
Suspensions
Multilayers

Keywords

  • graphene nanoflowers
  • multi-layer graphene
  • poly(vinylidene fluoride)
  • ultrasonic spray
  • adhesion

Cite this

Modesto-López, L. B., Miettinen, M., Torvela, T., Lähde, A., & Jokiniemi, J. (2015). Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying. Thin Solid Films, 578, 45-52. https://doi.org/10.1016/j.tsf.2015.01.073
Modesto-López, Luis B. ; Miettinen, Mirella ; Torvela, Tiina ; Lähde, Anna ; Jokiniemi, Jorma. / Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying. In: Thin Solid Films. 2015 ; Vol. 578. pp. 45-52.
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abstract = "In this work, suspensions of two types of graphene nanomaterials - graphene nanoflowers (GNFs) and multilayer graphene (MLG) flakes - were ultrasonically sprayed into micrometer-sized droplets to directly form films on glass and methacrylic acid copolymer (MA)-modified glass substrates. Poly(vinylidene fluoride) (PVDF) was added to the suspensions to enhance the structural robustness of films. While PVDF enhanced nanomaterial binding, the MA coating boosted nanomaterial adhesion to the substrate. The films' morphology, adhesion, and electrical properties were investigated. MLG flakes produced highly irregular films, conversely GNFs formed thinner and more uniform layers. In the case of MLG flakes, films on MA-coated glass showed lower resistances compared to those on glass. GNF suspensions sprayed on MA-coated glass resulted in graphene nanostructures embedded in a predominantly dielectric polymer matrix. Thus, in the case of GNFs, films on glass exhibited lower resistances compared to those on MA-coated glass. The approach described herein can be readily extended to create films of other graphene-based materials on a variety of substrates.",
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Modesto-López, LB, Miettinen, M, Torvela, T, Lähde, A & Jokiniemi, J 2015, 'Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying', Thin Solid Films, vol. 578, pp. 45-52. https://doi.org/10.1016/j.tsf.2015.01.073

Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying. / Modesto-López, Luis B. (Corresponding Author); Miettinen, Mirella; Torvela, Tiina; Lähde, Anna; Jokiniemi, Jorma.

In: Thin Solid Films, Vol. 578, 2015, p. 45-52.

Research output: Contribution to journalArticleScientificpeer-review

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T1 - Direct deposition of graphene nanomaterial films on polymer-coated glass by ultrasonic spraying

AU - Modesto-López, Luis B.

AU - Miettinen, Mirella

AU - Torvela, Tiina

AU - Lähde, Anna

AU - Jokiniemi, Jorma

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AB - In this work, suspensions of two types of graphene nanomaterials - graphene nanoflowers (GNFs) and multilayer graphene (MLG) flakes - were ultrasonically sprayed into micrometer-sized droplets to directly form films on glass and methacrylic acid copolymer (MA)-modified glass substrates. Poly(vinylidene fluoride) (PVDF) was added to the suspensions to enhance the structural robustness of films. While PVDF enhanced nanomaterial binding, the MA coating boosted nanomaterial adhesion to the substrate. The films' morphology, adhesion, and electrical properties were investigated. MLG flakes produced highly irregular films, conversely GNFs formed thinner and more uniform layers. In the case of MLG flakes, films on MA-coated glass showed lower resistances compared to those on glass. GNF suspensions sprayed on MA-coated glass resulted in graphene nanostructures embedded in a predominantly dielectric polymer matrix. Thus, in the case of GNFs, films on glass exhibited lower resistances compared to those on MA-coated glass. The approach described herein can be readily extended to create films of other graphene-based materials on a variety of substrates.

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