Abstract
We study the driven transport of polymers in a
periodically patterned channel using Langevin dynamics
simulations in two dimensions. The channel walls are
patterned with periodically alternating patches of
attractive and non-attractive particles that act as
trapping sites for the polymer. We find that the system
shows rich dynamical behavior, observing giant diffusion,
negative differential mobility, and several different
transition mechanisms between the attractive patches. We
also show that the channel can act as an efficient
high-pass filter for polymers longer than a threshold
length N thr, which can be tuned by adjusting the length
of the attractive patches and the driving force. Our
findings suggest the possibility of fabricating polymer
filtration devices based on patterned nanochannels
Original language | English |
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Article number | 234906 |
Journal | Journal of Chemical Physics |
Volume | 140 |
Issue number | 23 |
DOIs | |
Publication status | Published - 2014 |
MoE publication type | A1 Journal article-refereed |