Effect of Co-fed Water on a Co-Pt-Si/γ-Al2O3Fischer-Tropsch Catalyst Modified with an Atomic Layer Deposited or Molecular Layer Deposition Overcoating

Niko Heikkinen (Corresponding Author), Laura Keskiväli, Jasmiina Palo, Matti Reinikainen, Matti Putkonen

Research output: Contribution to journalArticleScientificpeer-review

Abstract

Atomic layer deposition (ALD) and molecular layer deposition (MLD) methods were used to prepare overcoatings on a cobalt-based Fischer-Tropsch catalyst. A Co-Pt-Si/γ-Al2O3catalyst (21.4 wt % Co, 0.2 wt % Pt, and 1.6 wt % Si) prepared by incipient wetness impregnation was ALD overcoated with 30-40 cycles of trimethylaluminum (TMA) and water, followed by temperature treatment (420 °C) in an inert nitrogen atmosphere. MLD-overcoated samples with corresponding film thicknesses were prepared by using TMA and ethylene glycol, followed by temperature treatment (400 °C) in an oxidative synthetic air atmosphere. The ALD catalyst (40 deposition cycles) had a positive activity effect upon moderate water addition (PH2O/PH2= 0.42), and compared with a non-overcoated catalyst, it showed resistance to irreversible deactivation after co-fed water conditions. In addition, MLD overcoatings had a positive effect on the catalyst activity upon moderate water addition. However, compared with a non-overcoated catalyst, only the 10-cycle MLD-overcoated catalyst retained increased activity throughout high added water conditions (PH2O/PH2= 0.71). All catalyst variations exhibited irreversible deactivation under high added water conditions.

Original languageEnglish
Pages (from-to)7725-7736
Number of pages12
JournalACS Omega
Volume7
Issue number9
DOIs
Publication statusPublished - 8 Mar 2022
MoE publication typeA1 Journal article-refereed

Funding

This research was funded by the European Union’s Horizon 2020 Research and Innovation program under grant agreement no. 768543 (ICO2CHEM project─From industrial CO streams to added value Fischer–Tropsch chemicals). M.P. acknowledges funding from the Academy of Finland by the profiling action on Matter and Materials, grant no. 318913. 2

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