Effect of high-temperature fiberization on the chemical structure of softwood

Petri Widsten, Jaakko E. Laine, Pia Qvintus-Leino, Simo Tuominen

Research output: Contribution to journalArticleScientificpeer-review

23 Citations (Scopus)

Abstract

Softwoods fiberized at high temperatures (above 170°C) were subjected to bulk and surface chemical analyses. It was found that the frequency of lignin β-O-4 linkages declined while that of phenolic hydroxyl groups increased with an increase in fiberization temperature. The amount of water extractable aromatic compounds increased with increasing temperature of fiberization, which was associated with cleavage of lignin ether linkages. The water extractable material generated was enriched in hemicelluloses and contained aromatic compounds rich in phenolic hydroxyl groups and low in β-O-4 linkages. The amount and hemicellulose content of the water extracts increased with increasing fiberization temperature. Lipophilic extractives covered most of the fiber surfaces while the surface lignin content of extractives-free fibers roughly doubled their bulk lignin content.

Original languageEnglish
Pages (from-to)227-245
Number of pages19
JournalJournal of Wood Chemistry and Technology
Volume21
Issue number3
DOIs
Publication statusPublished - 2001
MoE publication typeNot Eligible

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Softwoods
Lignin
Aromatic compounds
Hydroxyl Radical
Water
Temperature
Fibers
Ether
Ethers
hemicellulose

Cite this

Widsten, Petri ; Laine, Jaakko E. ; Qvintus-Leino, Pia ; Tuominen, Simo. / Effect of high-temperature fiberization on the chemical structure of softwood. In: Journal of Wood Chemistry and Technology. 2001 ; Vol. 21, No. 3. pp. 227-245.
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Effect of high-temperature fiberization on the chemical structure of softwood. / Widsten, Petri; Laine, Jaakko E.; Qvintus-Leino, Pia; Tuominen, Simo.

In: Journal of Wood Chemistry and Technology, Vol. 21, No. 3, 2001, p. 227-245.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Effect of high-temperature fiberization on the chemical structure of softwood

AU - Widsten, Petri

AU - Laine, Jaakko E.

AU - Qvintus-Leino, Pia

AU - Tuominen, Simo

PY - 2001

Y1 - 2001

N2 - Softwoods fiberized at high temperatures (above 170°C) were subjected to bulk and surface chemical analyses. It was found that the frequency of lignin β-O-4 linkages declined while that of phenolic hydroxyl groups increased with an increase in fiberization temperature. The amount of water extractable aromatic compounds increased with increasing temperature of fiberization, which was associated with cleavage of lignin ether linkages. The water extractable material generated was enriched in hemicelluloses and contained aromatic compounds rich in phenolic hydroxyl groups and low in β-O-4 linkages. The amount and hemicellulose content of the water extracts increased with increasing fiberization temperature. Lipophilic extractives covered most of the fiber surfaces while the surface lignin content of extractives-free fibers roughly doubled their bulk lignin content.

AB - Softwoods fiberized at high temperatures (above 170°C) were subjected to bulk and surface chemical analyses. It was found that the frequency of lignin β-O-4 linkages declined while that of phenolic hydroxyl groups increased with an increase in fiberization temperature. The amount of water extractable aromatic compounds increased with increasing temperature of fiberization, which was associated with cleavage of lignin ether linkages. The water extractable material generated was enriched in hemicelluloses and contained aromatic compounds rich in phenolic hydroxyl groups and low in β-O-4 linkages. The amount and hemicellulose content of the water extracts increased with increasing fiberization temperature. Lipophilic extractives covered most of the fiber surfaces while the surface lignin content of extractives-free fibers roughly doubled their bulk lignin content.

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DO - 10.1081/WCT-100105374

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