Effect of impurities in precious metal recovery by electrodeposition-redox replacement method from industrial side-streams and process streams

Kirsi Yliniemi, Zulin Wang, Ivan Korolev, Pyry-Mikko Hannula, Petteri Halli, Mari Lundström (Corresponding Author)

Research output: Contribution to journalArticle in a proceedings journalScientificpeer-review

21 Citations (Scopus)

Abstract

The recovery of precious metals (Ag and Au) by electrodeposition-redox replacement (EDRR) method was studied in three different solutions: sulfate based Zn-Fe-Ag solution, chloride based Cu-Fe-Au solution and industrial multi-metal chloride solution. The common factor to these solutions is that the base metal (Zn or Cu) is present in g/L scale while the precious metal is present in ppm or lower level. The results showed that the presence of impurity Fe (in g/L scale) decreases the recovery efficiency of precious metals but at the same time, it may lead to selective dissolution of the base metal, resulting in the higher purity of the precious metal deposit. Moreover, a successful deposition of Au on carbon nanotube (CNT) films from industrial multi-metal solution was demonstrated.

Original languageEnglish
Pages (from-to)59-67
Number of pages9
JournalECS Transactions
Volume85
Issue number4
DOIs
Publication statusPublished - 2018
MoE publication typeA4 Article in a conference publication
Event233rd ECS Meeting Symposium on Industrial Electrochemistry and Electrochemical Engineering General Session - - Seattle, United States
Duration: 13 May 201817 May 2018

Funding

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