Effect of preparation methods on properties of alumina/titanias

Makoto Toba, Fujio Mizukami, Shu-ichi Niwa, Yoshimichi Kiozumi, Kazuyuki Maeda, Arto Annila, Veikko Komppa

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Abstract

Alumina/titanias have been prepared by three methods: complexing-agent-assisted sol–gel; coprecipitation; and hydrogel kneading. The relationship between the preparation methods and the properties of the alumina/titanias was investigated by thermal gravimetry and differential thermal analysis (TG–DTA), X-ray powder diffraction, laser Raman spectroscopy, solid-state magic-angle spinning nuclear magnetic resonance (MAS-NMR), ammonia temperature-programmed desorption (TPD) and nitrogen adsorption. Of the three preparation methods, the complexing-agent-assisted sol–gel method gave the most homogeneous alumina/titanias, and their acidities and specific surface areas depended on complexing agents used in the preparation and the Ti:Al ratios of the raw materials. In contrast, kneading alumina/titanias were relatively heterogeneous and their properties did not depend on the Ti:Al ratio. Regarding the dependences of properties of alumina/titanias on the Ti:Al ratio, coprecipitation alumina/titanias are intermediate between complexing-agent-assisted sol–gel and kneading ones.
Original languageEnglish
Pages (from-to)585-589
Number of pages5
JournalJournal of Materials Chemistry
Volume4
Issue number4
DOIs
Publication statusPublished - 1994
MoE publication typeA1 Journal article-refereed

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Toba, M., Mizukami, F., Niwa, S., Kiozumi, Y., Maeda, K., Annila, A., & Komppa, V. (1994). Effect of preparation methods on properties of alumina/titanias. Journal of Materials Chemistry, 4(4), 585-589. https://doi.org/10.1039/JM9940400585