Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons

Virpi Siipola; Tarja Tamminen; Anssi Källi; Riikka Lahti; Henrik Romar; Kimmo Rasa; Riikka Keskinen; Jari Hyväluoma; Markus Hannula; Hanne Wikberg

Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons

Virpi Siipola (Corresponding Author), Tarja Tamminen, Anssi Källi, Riikka Lahti, Henrik Romar, Kimmo Rasa, Riikka Keskinen, Jari Hyväluoma, Markus Hannula, Hanne Wikberg

Research output: Contribution to journal › Article › Scientific › peer-review

7 Citations (Scopus)

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Abstract

Activated carbons (AC) serve as adsorbents in various applications requiring specific functionalities. In this study, the effects of biomass type, pre-carbonization process, and activation method on the properties of ACs were investigated. Chemical (KOH and H3PO4) and physical (CO2) activations were performed on slow pyrolyzed and hydrothermally carbonized (HTC) biochars produced from two feedstocks, willow and Scots pine bark (SPB). In addition, the adsorption capacities of the ACs were tested with two dyes and zinc metal. Distinct differences were found between the biochars and ACs regarding pore size distributions, surface area (238 - 3505 m2 g-1), and surface chemistry. KOH activation produced highly microporous ACs from all biochars, whereas with H3PO4 and CO2 there was also increase in the meso- and macroporosity with the HTC biochars. Adsorption capacity for dyes was dependent on the surface area, while for zinc it depended on AC’s pH. The results provide interesting insights into tailoring ACs for specific applications.

Original language	English
Pages (from-to)	5976-6002
Number of pages	27
Journal	BioResources
Volume	13
Issue number	3
Publication status	Published - 15 Jun 2018
MoE publication type	A1 Journal article-refereed

Keywords

Biochar
Activated carbon;
Bio-based activated carbon
Willow
Pine bark
X-ray tomography

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Siipola, V., Tamminen, T., Källi, A., Lahti, R., Romar, H., Rasa, K., Keskinen, R., Hyväluoma, J., Hannula, M., & Wikberg, H. (2018). Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons. BioResources, 13(3), 5976-6002. https://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_13_3_5976_Siipola_Biomass_Type_Carbonization_Process_Activation_Method

@article{2105ca502166497fa8d9db2097ea85ce,

title = "Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons",

abstract = "Activated carbons (AC) serve as adsorbents in various applications requiring specific functionalities. In this study, the effects of biomass type, pre-carbonization process, and activation method on the properties of ACs were investigated. Chemical (KOH and H3PO4) and physical (CO2) activations were performed on slow pyrolyzed and hydrothermally carbonized (HTC) biochars produced from two feedstocks, willow and Scots pine bark (SPB). In addition, the adsorption capacities of the ACs were tested with two dyes and zinc metal. Distinct differences were found between the biochars and ACs regarding pore size distributions, surface area (238 - 3505 m2 g-1), and surface chemistry. KOH activation produced highly microporous ACs from all biochars, whereas with H3PO4 and CO2 there was also increase in the meso- and macroporosity with the HTC biochars. Adsorption capacity for dyes was dependent on the surface area, while for zinc it depended on AC{\textquoteright}s pH. The results provide interesting insights into tailoring ACs for specific applications.",

keywords = "Biochar, Activated carbon;, Bio-based activated carbon, Willow, Pine bark, X-ray tomography",

author = "Virpi Siipola and Tarja Tamminen and Anssi K{\"a}lli and Riikka Lahti and Henrik Romar and Kimmo Rasa and Riikka Keskinen and Jari Hyv{\"a}luoma and Markus Hannula and Hanne Wikberg",

year = "2018",

month = jun,

day = "15",

language = "English",

volume = "13",

pages = "5976--6002",

journal = "BioResources",

issn = "1930-2126",

publisher = "North Carolina State University",

number = "3",

}

Siipola, V , Tamminen, T , Källi, A, Lahti, R, Romar, H, Rasa, K, Keskinen, R, Hyväluoma, J, Hannula, M & Wikberg, H 2018, 'Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons', BioResources, vol. 13, no. 3, pp. 5976-6002. <https://ojs.cnr.ncsu.edu/index.php/BioRes/article/view/BioRes_13_3_5976_Siipola_Biomass_Type_Carbonization_Process_Activation_Method>

Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons. / Siipola, Virpi (Corresponding Author); Tamminen, Tarja ; Källi, Anssi; Lahti, Riikka; Romar, Henrik; Rasa, Kimmo; Keskinen, Riikka; Hyväluoma, Jari; Hannula, Markus; Wikberg, Hanne.

In: BioResources, Vol. 13, No. 3, 15.06.2018, p. 5976-6002.

Research output: Contribution to journal › Article › Scientific › peer-review

TY - JOUR

T1 - Effects of Biomass Type, Carbonization Process, and Activation Method on the Properties of Bio-Based Activated Carbons

AU - Siipola, Virpi

AU - Tamminen, Tarja

AU - Källi, Anssi

AU - Lahti, Riikka

AU - Romar, Henrik

AU - Rasa, Kimmo

AU - Keskinen, Riikka

AU - Hyväluoma, Jari

AU - Hannula, Markus

AU - Wikberg, Hanne

PY - 2018/6/15

Y1 - 2018/6/15

N2 - Activated carbons (AC) serve as adsorbents in various applications requiring specific functionalities. In this study, the effects of biomass type, pre-carbonization process, and activation method on the properties of ACs were investigated. Chemical (KOH and H3PO4) and physical (CO2) activations were performed on slow pyrolyzed and hydrothermally carbonized (HTC) biochars produced from two feedstocks, willow and Scots pine bark (SPB). In addition, the adsorption capacities of the ACs were tested with two dyes and zinc metal. Distinct differences were found between the biochars and ACs regarding pore size distributions, surface area (238 - 3505 m2 g-1), and surface chemistry. KOH activation produced highly microporous ACs from all biochars, whereas with H3PO4 and CO2 there was also increase in the meso- and macroporosity with the HTC biochars. Adsorption capacity for dyes was dependent on the surface area, while for zinc it depended on AC’s pH. The results provide interesting insights into tailoring ACs for specific applications.

AB - Activated carbons (AC) serve as adsorbents in various applications requiring specific functionalities. In this study, the effects of biomass type, pre-carbonization process, and activation method on the properties of ACs were investigated. Chemical (KOH and H3PO4) and physical (CO2) activations were performed on slow pyrolyzed and hydrothermally carbonized (HTC) biochars produced from two feedstocks, willow and Scots pine bark (SPB). In addition, the adsorption capacities of the ACs were tested with two dyes and zinc metal. Distinct differences were found between the biochars and ACs regarding pore size distributions, surface area (238 - 3505 m2 g-1), and surface chemistry. KOH activation produced highly microporous ACs from all biochars, whereas with H3PO4 and CO2 there was also increase in the meso- and macroporosity with the HTC biochars. Adsorption capacity for dyes was dependent on the surface area, while for zinc it depended on AC’s pH. The results provide interesting insights into tailoring ACs for specific applications.

KW - Biochar

KW - Activated carbon;

KW - Bio-based activated carbon

KW - Willow

KW - Pine bark

KW - X-ray tomography

UR - http://www.scopus.com/inward/record.url?scp=85064618805&partnerID=8YFLogxK

M3 - Article

VL - 13

SP - 5976

EP - 6002

JO - BioResources

JF - BioResources

SN - 1930-2126

IS - 3

ER -