Abstract
In the hydrogenation of carbon monoxide, alkali cations were found to be effective as modifiers for highly dispersed cobalt catalyst to improve the selectivities of C2-oxygenated compounds, especially acetic acid and acetaldehyde, and to increase the olefin/paraffin ratio of hydrocarbons. These effects are ascribed to depression of the hydrogenating ability of the catalyst by modification with alkali cations.
| Original language | English |
|---|---|
| Pages (from-to) | 193 - 200 |
| Number of pages | 8 |
| Journal | Catalysis Letters |
| Volume | 10 |
| Issue number | 3-4 |
| DOIs | |
| Publication status | Published - 1991 |
| MoE publication type | A1 Journal article-refereed |
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Effects of modification of highly dispersed cobalt catalysts with alkali cations on the hydrogenation of carbon monoxide. / Matsuzaki, Takehiko; Hanaoka, Taka-aki; Takeuchi, Kazuhiko; Sugi, Yoshihiro; Reinikainen, Matti.
In: Catalysis Letters, Vol. 10, No. 3-4, 1991, p. 193 - 200.Research output: Contribution to journal › Article › Scientific › peer-review
TY - JOUR
T1 - Effects of modification of highly dispersed cobalt catalysts with alkali cations on the hydrogenation of carbon monoxide
AU - Matsuzaki, Takehiko
AU - Hanaoka, Taka-aki
AU - Takeuchi, Kazuhiko
AU - Sugi, Yoshihiro
AU - Reinikainen, Matti
N1 - Project code: KEM6010
PY - 1991
Y1 - 1991
N2 - In the hydrogenation of carbon monoxide, alkali cations were found to be effective as modifiers for highly dispersed cobalt catalyst to improve the selectivities of C2-oxygenated compounds, especially acetic acid and acetaldehyde, and to increase the olefin/paraffin ratio of hydrocarbons. These effects are ascribed to depression of the hydrogenating ability of the catalyst by modification with alkali cations.
AB - In the hydrogenation of carbon monoxide, alkali cations were found to be effective as modifiers for highly dispersed cobalt catalyst to improve the selectivities of C2-oxygenated compounds, especially acetic acid and acetaldehyde, and to increase the olefin/paraffin ratio of hydrocarbons. These effects are ascribed to depression of the hydrogenating ability of the catalyst by modification with alkali cations.
U2 - 10.1007/BF00772071
DO - 10.1007/BF00772071
M3 - Article
VL - 10
SP - 193
EP - 200
JO - Catalysis Letters
JF - Catalysis Letters
SN - 1011-372X
IS - 3-4
ER -