Abstract
The effects of thermal stress on the breakdown behavior of biaxially oriented PP-silica nanocomposite thin film and commercial BOPP film was evaluated with a step stress experiment in the temperature range of 50...110 °C. Weak spots were measured in thermally aged un-filled BOPP films but not in the PP-silica, which in turn displayed increasing scatter of the breakdown voltages and the scattering seemingly settled to a certain level. No weak spots were measured in un-filled BOPP films removed after highest temperatures. The behavior of un-filled films is speculated to result from either actual polymer aging in addition to the statistical nature of breakdown phenomena or from thermally-activated processes possibly involving antioxidants. The different behavior in the nanocomposite was speculated to result from polymer-nanoparticle interactions possibly countering the effects of antioxidants and hindering weak spot formation. The results demonstrate the different behavior of polymer-nanocomposites and traditional BOPP films under thermal stress and highlight the importance of evaluating the aging behavior of new materials.
| Original language | English |
|---|---|
| Title of host publication | Properties and Applications of Dielectric Materials (ICPADM), 2015 IEEE 11th International Conference on the |
| Publisher | IEEE Institute of Electrical and Electronic Engineers |
| Pages | 400-403 |
| ISBN (Electronic) | 978-1-4799-8903-4, 978-1-4799-8902-7 |
| DOIs | |
| Publication status | Published - 15 Oct 2015 |
| MoE publication type | A4 Article in a conference publication |
| Event | IEEE 11th International Conference on the Properties and Applications of Dielectric Materials, ICPADM 2015 - Sydney, Australia Duration: 19 Jul 2015 → 22 Jul 2015 Conference number: 11 |
Conference
| Conference | IEEE 11th International Conference on the Properties and Applications of Dielectric Materials, ICPADM 2015 |
|---|---|
| Abbreviated title | ICPADM 2015 |
| Country/Territory | Australia |
| City | Sydney |
| Period | 19/07/15 → 22/07/15 |
Keywords
- BOPP film
- thermal stress
- breakdown