An electrically conductive nanocomposite composed of thermoplastic elastomer and nanosized silver particles was developed. Nanosized silver particles were produced by the liquid flame spraying method. Nanocomposites were produced employing a batch mixing process in the melt state. The percolation curve and the minimum resistivity as a function of silver content were defined. A plasticized styrene block-copolymer was used as the matrix polymer. The results showed that the agglomeration of the silver particles has a major influence on the percolation threshold and the resistivity of the compound. With slightly agglomerated silver particles a percolation threshold with a silver content of 13–16 vol.% was achieved. The corresponding resistivity was 2.0 × 10−1 Ω cm. With heavily agglomerated particles the resistivity is high (2.9 × 103 Ω cm), even with a silver content of 20 vol.%. With a low primary silver particle size (under 100 nm), the resistivity of the compound was high (5.6 × 105 Ω cm).
- electronic materials
Karttunen, M., Ruuskanen, P., Pitkänen, V., & Albers, W. M. (2008). Electrically conductive metal polymer nanocomposites for electronics applications. Journal of Electronic Materials, 37(7), 951-954. https://doi.org/10.1007/s11664-008-0451-2