Electrospinning of polyamides with different chain compositions for filtration application

Pirjo Heikkilä (Corresponding Author), Aimo Taipale, Matti Lehtimäki, Ali Harlin

Research output: Contribution to journalArticleScientificpeer-review

64 Citations (Scopus)

Abstract

Electrospinning of several polyamides, PA6, PA66, PA612, PA614, PA1012, and PA1014, having different chain compositions and lengths of diacid and diamine segments, was demonstrated. Electrospinnability and fiber production rate of these polyamides were evaluated. Electrospun fibers were characterized with regard to their use in air filtration by measuring fiber diameter and filtration efficiency of fiber coating. Longer nonpolar chain segments of higher polyamides could in theory indicate higher dielectricity compared to PA6 and PA66, which would be an advantage in filtration applications. The solubility in polar formic acid and electrospinnability of higher polyamides, on the other hand, were clearly impaired with increased length of chain segments. Hence, PA66 is our best choice, and PA612 and PA6 our second options for commercial filtration applications if fiber electrospinnability, production rate, fiber diameter, and its distribution are concerned. Filtration efficiency of more than 95% of the particles having a diameter of 0.16 μm and above was achieved with 0.5 g/m2 coating of PA66 nanofibers. Further increase in coating weight mainly increased the pressure drop to an unusable range without a significant further improvement of filtration efficiency.
Original languageEnglish
Pages (from-to)1168 - 1176
Number of pages9
JournalPolymer Engineering and Science
Volume48
Issue number6
DOIs
Publication statusPublished - 2008
MoE publication typeA1 Journal article-refereed

Fingerprint

Nylons
Electrospinning
Polyamides
Fibers
Chemical analysis
formic acid
Coatings
Diamines
Formic acid
Nanofibers
Pressure drop
Solubility
Air

Keywords

  • electrospinning
  • polyamide
  • air filtration

Cite this

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title = "Electrospinning of polyamides with different chain compositions for filtration application",
abstract = "Electrospinning of several polyamides, PA6, PA66, PA612, PA614, PA1012, and PA1014, having different chain compositions and lengths of diacid and diamine segments, was demonstrated. Electrospinnability and fiber production rate of these polyamides were evaluated. Electrospun fibers were characterized with regard to their use in air filtration by measuring fiber diameter and filtration efficiency of fiber coating. Longer nonpolar chain segments of higher polyamides could in theory indicate higher dielectricity compared to PA6 and PA66, which would be an advantage in filtration applications. The solubility in polar formic acid and electrospinnability of higher polyamides, on the other hand, were clearly impaired with increased length of chain segments. Hence, PA66 is our best choice, and PA612 and PA6 our second options for commercial filtration applications if fiber electrospinnability, production rate, fiber diameter, and its distribution are concerned. Filtration efficiency of more than 95{\%} of the particles having a diameter of 0.16 μm and above was achieved with 0.5 g/m2 coating of PA66 nanofibers. Further increase in coating weight mainly increased the pressure drop to an unusable range without a significant further improvement of filtration efficiency.",
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Electrospinning of polyamides with different chain compositions for filtration application. / Heikkilä, Pirjo (Corresponding Author); Taipale, Aimo; Lehtimäki, Matti; Harlin, Ali.

In: Polymer Engineering and Science, Vol. 48, No. 6, 2008, p. 1168 - 1176.

Research output: Contribution to journalArticleScientificpeer-review

TY - JOUR

T1 - Electrospinning of polyamides with different chain compositions for filtration application

AU - Heikkilä, Pirjo

AU - Taipale, Aimo

AU - Lehtimäki, Matti

AU - Harlin, Ali

PY - 2008

Y1 - 2008

N2 - Electrospinning of several polyamides, PA6, PA66, PA612, PA614, PA1012, and PA1014, having different chain compositions and lengths of diacid and diamine segments, was demonstrated. Electrospinnability and fiber production rate of these polyamides were evaluated. Electrospun fibers were characterized with regard to their use in air filtration by measuring fiber diameter and filtration efficiency of fiber coating. Longer nonpolar chain segments of higher polyamides could in theory indicate higher dielectricity compared to PA6 and PA66, which would be an advantage in filtration applications. The solubility in polar formic acid and electrospinnability of higher polyamides, on the other hand, were clearly impaired with increased length of chain segments. Hence, PA66 is our best choice, and PA612 and PA6 our second options for commercial filtration applications if fiber electrospinnability, production rate, fiber diameter, and its distribution are concerned. Filtration efficiency of more than 95% of the particles having a diameter of 0.16 μm and above was achieved with 0.5 g/m2 coating of PA66 nanofibers. Further increase in coating weight mainly increased the pressure drop to an unusable range without a significant further improvement of filtration efficiency.

AB - Electrospinning of several polyamides, PA6, PA66, PA612, PA614, PA1012, and PA1014, having different chain compositions and lengths of diacid and diamine segments, was demonstrated. Electrospinnability and fiber production rate of these polyamides were evaluated. Electrospun fibers were characterized with regard to their use in air filtration by measuring fiber diameter and filtration efficiency of fiber coating. Longer nonpolar chain segments of higher polyamides could in theory indicate higher dielectricity compared to PA6 and PA66, which would be an advantage in filtration applications. The solubility in polar formic acid and electrospinnability of higher polyamides, on the other hand, were clearly impaired with increased length of chain segments. Hence, PA66 is our best choice, and PA612 and PA6 our second options for commercial filtration applications if fiber electrospinnability, production rate, fiber diameter, and its distribution are concerned. Filtration efficiency of more than 95% of the particles having a diameter of 0.16 μm and above was achieved with 0.5 g/m2 coating of PA66 nanofibers. Further increase in coating weight mainly increased the pressure drop to an unusable range without a significant further improvement of filtration efficiency.

KW - electrospinning

KW - polyamide

KW - air filtration

U2 - 10.1002/pen.21070

DO - 10.1002/pen.21070

M3 - Article

VL - 48

SP - 1168

EP - 1176

JO - Polymer Engineering and Science

JF - Polymer Engineering and Science

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