Experimental study of SOFC system heat-up without safety gases

Matias Halinen (Corresponding Author), Olivier Thomann, Jari Kiviaho

    Research output: Contribution to journalArticleScientificpeer-review

    23 Citations (Scopus)


    Premixed safety gas is conventionally used to keep the anode of a solid oxide fuel cell (SOFC) under reducing conditions during heat-up. This article presents the results of an experimental study to heat up a SOFC system and stack without the said premixed safety gases, i.e. by utilizing a natural gas pre-reformer and anode off-gas recycling (AOGR). Firstly, ex-situ experiments were conducted to investigate the operability of a pre-reformer during system heat-up. It was found that any oxygen fed to the reformer hinders the reforming reactions at low temperatures. Secondly, based on the ex-situ findings, series of heat-up cycles were conducted with a complete 10 kW system using AOGR and a planar SOFC stack. In these experiments it was found that the system heat-up is possible with fuel gas and steam only, without the need for premixed reducing safety gases. Use of the fuel gas instead of a premixed safety gas did not result in a significant performance loss in the SOFC stack. Therefore, such a heat-up strategy was developed for SOFC systems that reduces the need of premixed safety gas storage space and thus decreases the system cost.
    Original languageEnglish
    Pages (from-to)552-561
    Number of pages10
    JournalInternational Journal of Hydrogen Energy
    Issue number1
    Publication statusPublished - 2014
    MoE publication typeA1 Journal article-refereed


    • anode off-gas recycling
    • heat-up
    • reformer
    • solid oxide fuel cell
    • start-up
    • system


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