Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization

Markku Auer; R. Nicolas; A. Vesterinen; H. Luttikhedde; Carl Wilen

doi:10.1002/pola.11082

Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization

Markku Auer, R. Nicolas, A. Vesterinen, H. Luttikhedde, Carl Wilen (Corresponding Author)

VTT Technical Research Centre of Finland

Research output: Contribution to journal › Article › Scientific › peer-review

10 Citations (Scopus)

Abstract

This work describes a facile method by which a polymerizable hindered amine light stabilizer, 4‐(10‐undecylidene)‐2,2,6,6‐tetramethylpiperidine, was prepared in a single‐step procedure by means of a Wittig reaction. The monomer was successfully copolymerized with ethylene with a rac‐[dimethylsilylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)]zirconium dichloride/methylalumoxane catalyst system.

Original language	English
Pages (from-to)	1350-1355
Journal	Journal of Polymer Science, Part A: Polymer Chemistry
Volume	42
Issue number	6
DOIs	https://doi.org/10.1002/pola.11082
Publication status	Published - 2004
MoE publication type	A1 Journal article-refereed

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10.1002/pola.11082

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title = "Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization",

abstract = "This work describes a facile method by which a polymerizable hindered amine light stabilizer, 4‐(10‐undecylidene)‐2,2,6,6‐tetramethylpiperidine, was prepared in a single‐step procedure by means of a Wittig reaction. The monomer was successfully copolymerized with ethylene with a rac‐[dimethylsilylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)]zirconium dichloride/methylalumoxane catalyst system. ",

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T1 - Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization

AU - Auer, Markku

AU - Nicolas, R.

AU - Vesterinen, A.

AU - Luttikhedde, H.

AU - Wilen, Carl

PY - 2004

Y1 - 2004

N2 - This work describes a facile method by which a polymerizable hindered amine light stabilizer, 4‐(10‐undecylidene)‐2,2,6,6‐tetramethylpiperidine, was prepared in a single‐step procedure by means of a Wittig reaction. The monomer was successfully copolymerized with ethylene with a rac‐[dimethylsilylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)]zirconium dichloride/methylalumoxane catalyst system.

AB - This work describes a facile method by which a polymerizable hindered amine light stabilizer, 4‐(10‐undecylidene)‐2,2,6,6‐tetramethylpiperidine, was prepared in a single‐step procedure by means of a Wittig reaction. The monomer was successfully copolymerized with ethylene with a rac‐[dimethylsilylenebis(4,5,6,7‐tetrahydro‐1‐indenyl)]zirconium dichloride/methylalumoxane catalyst system.

U2 - 10.1002/pola.11082

DO - 10.1002/pola.11082

M3 - Article

SN - 0887-624X

VL - 42

SP - 1350

EP - 1355

JO - Journal of Polymer Science, Part A: Polymer Chemistry

JF - Journal of Polymer Science, Part A: Polymer Chemistry

IS - 6

ER -

Facile synthetic route to polymerizable hindered amine light stabilizers for transition-metal-catalyzed olefin copolymerization

Abstract

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