Fate of some trace elements in fluidised-bed combustion and gasification processes

Wahab Mojtahedi, Rainer Backman, Kari Larjava

Research output: Book/ReportReportProfessional

19 Citations (Scopus)

Abstract

Coal and municipal waste (MSW) contain many trace elements which are released upon combustion and gasification and have toxic forms at certain concentrations.These pollutants must be removed, if increasingly stricter emission standards are to be met.Four metals, namely: cadmium (Cd), lead (Pb), zinc (Zn), and mercury (Hg), were selected for study and multicomponent, multiphase equilibrium calculations were carried out to determine which elements volatilise upon combustion and gasification and which ones condense upon cooling the flue gases.It was also intended to determine the distribution of the trace element species in the product streams.Both fluidised bed combustion and gasification processes were studied having coal and municipal solid waste as fuel.A temperature range of 200-1 300 °C and two operating pressures of 1 and 10 bar were employed.Air ratio was varied from 0.3 to 2.0, under both operating pressures.The results show some interesting changes in the composition of the combustion gases with changes in temperature as well as with the air ratio.Cd, Hg, and Pb seem to be totally volatilised at 700-900 °C temperature range, but Zn only partially.Upon cooling, sulphates are formed in oxidising, but sulphides in reducing atmosphere.
Original languageEnglish
Place of PublicationEspoo
PublisherVTT Technical Research Centre of Finland
Number of pages49
ISBN (Print)951-38-2979-0
Publication statusPublished - 1987
MoE publication typeNot Eligible

Publication series

NamePublications / Technical Research Centre of Finland
PublisherVTT
No.42
ISSN (Print)0358-5069

Fingerprint

combustion
trace element
cadmium
zinc
coal
cooling
temperature
air
municipal solid waste
sulfide
sulfate
pollutant
atmosphere
metal
gasification
fluidised bed
municipal waste
combustion gas
flue gas
distribution

Keywords

  • fluidized beds
  • coal
  • wastes
  • combustion
  • gasification
  • fluidized bed processors
  • flue gases
  • pollution
  • trace elements
  • heavy metals

Cite this

Mojtahedi, W., Backman, R., & Larjava, K. (1987). Fate of some trace elements in fluidised-bed combustion and gasification processes. Espoo: VTT Technical Research Centre of Finland. Technical Research Centre of Finland. Publications , No. 42
Mojtahedi, Wahab ; Backman, Rainer ; Larjava, Kari. / Fate of some trace elements in fluidised-bed combustion and gasification processes. Espoo : VTT Technical Research Centre of Finland, 1987. 49 p. (Technical Research Centre of Finland. Publications ; No. 42).
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Mojtahedi, W, Backman, R & Larjava, K 1987, Fate of some trace elements in fluidised-bed combustion and gasification processes. Technical Research Centre of Finland. Publications , no. 42, VTT Technical Research Centre of Finland, Espoo.

Fate of some trace elements in fluidised-bed combustion and gasification processes. / Mojtahedi, Wahab; Backman, Rainer; Larjava, Kari.

Espoo : VTT Technical Research Centre of Finland, 1987. 49 p. (Technical Research Centre of Finland. Publications ; No. 42).

Research output: Book/ReportReportProfessional

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AU - Larjava, Kari

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N2 - Coal and municipal waste (MSW) contain many trace elements which are released upon combustion and gasification and have toxic forms at certain concentrations.These pollutants must be removed, if increasingly stricter emission standards are to be met.Four metals, namely: cadmium (Cd), lead (Pb), zinc (Zn), and mercury (Hg), were selected for study and multicomponent, multiphase equilibrium calculations were carried out to determine which elements volatilise upon combustion and gasification and which ones condense upon cooling the flue gases.It was also intended to determine the distribution of the trace element species in the product streams.Both fluidised bed combustion and gasification processes were studied having coal and municipal solid waste as fuel.A temperature range of 200-1 300 °C and two operating pressures of 1 and 10 bar were employed.Air ratio was varied from 0.3 to 2.0, under both operating pressures.The results show some interesting changes in the composition of the combustion gases with changes in temperature as well as with the air ratio.Cd, Hg, and Pb seem to be totally volatilised at 700-900 °C temperature range, but Zn only partially.Upon cooling, sulphates are formed in oxidising, but sulphides in reducing atmosphere.

AB - Coal and municipal waste (MSW) contain many trace elements which are released upon combustion and gasification and have toxic forms at certain concentrations.These pollutants must be removed, if increasingly stricter emission standards are to be met.Four metals, namely: cadmium (Cd), lead (Pb), zinc (Zn), and mercury (Hg), were selected for study and multicomponent, multiphase equilibrium calculations were carried out to determine which elements volatilise upon combustion and gasification and which ones condense upon cooling the flue gases.It was also intended to determine the distribution of the trace element species in the product streams.Both fluidised bed combustion and gasification processes were studied having coal and municipal solid waste as fuel.A temperature range of 200-1 300 °C and two operating pressures of 1 and 10 bar were employed.Air ratio was varied from 0.3 to 2.0, under both operating pressures.The results show some interesting changes in the composition of the combustion gases with changes in temperature as well as with the air ratio.Cd, Hg, and Pb seem to be totally volatilised at 700-900 °C temperature range, but Zn only partially.Upon cooling, sulphates are formed in oxidising, but sulphides in reducing atmosphere.

KW - fluidized beds

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KW - heavy metals

M3 - Report

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Mojtahedi W, Backman R, Larjava K. Fate of some trace elements in fluidised-bed combustion and gasification processes. Espoo: VTT Technical Research Centre of Finland, 1987. 49 p. (Technical Research Centre of Finland. Publications ; No. 42).