Fourier transform infrared photoacoustic multicomponent gas spectroscopy with optical cantilever detection

Christian Hirschmann (Corresponding Author), J. Uotila, Satu Ojala, Jussi Tenhunen, R. L. Keiski

Research output: Contribution to journalArticleScientificpeer-review

9 Citations (Scopus)

Abstract

The sensitivity of photoacoustic spectroscopy was improved with the invention of optical cantilever detection (PAS-OCD). However, the ability of present PAS-OCD devices to carry out multicomponent detection is poor. To overcome this, a Fourier transform infrared photoacoustic spectrometer with optical cantilever detection (FT-IR-PAS-OCD) prototype was assembled. In this article, the first evaluation and performance tests of the prototype are described. Selectivity, sensitivity, and the linearity of the signal response are evaluated. The linear response was studied for methane and carbon dioxide and confirmed in the whole analyzed concentration range from 500 to 3500 ppm and from 2500 to 17500 ppm, respectively. The calculated signal-to-noise ratio (SNR) and limit of detection were 2027 and 0.5 ppm for methane and 1362 and 4 ppm for carbon dioxide, with a measurement time of 100 seconds. Selectivity was studied with a multicomponent gas mixture of propene, methane, carbon dioxide, and methylmercaptane. The results indicate that a quantitative analysis of all components in the mixture is possible using the FT-IR-PAS-OCD.
Original languageEnglish
Pages (from-to)293-297
Number of pages5
JournalApplied Spectroscopy
Volume64
Issue number3
DOIs
Publication statusPublished - 2010
MoE publication typeA1 Journal article-refereed

Fingerprint

gas spectroscopy
PAS
photoacoustic spectroscopy
Photoacoustic effect
Methane
Carbon Dioxide
Carbon dioxide
Fourier transforms
Gases
Spectroscopy
Infrared radiation
carbon dioxide
methane
Photoacoustic spectroscopy
selectivity
prototypes
Patents and inventions
Time measurement
Gas mixtures
inventions

Keywords

  • Photoacoustic spectroscopy
  • PAS
  • Fourier transform infrared spectroscopy
  • FT-IR spectroscopy
  • Cantilever microphone
  • Optical cantilever detection
  • OCD
  • Multicomponent gas mixture
  • Linearity

Cite this

Hirschmann, Christian ; Uotila, J. ; Ojala, Satu ; Tenhunen, Jussi ; Keiski, R. L. / Fourier transform infrared photoacoustic multicomponent gas spectroscopy with optical cantilever detection. In: Applied Spectroscopy. 2010 ; Vol. 64, No. 3. pp. 293-297.
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abstract = "The sensitivity of photoacoustic spectroscopy was improved with the invention of optical cantilever detection (PAS-OCD). However, the ability of present PAS-OCD devices to carry out multicomponent detection is poor. To overcome this, a Fourier transform infrared photoacoustic spectrometer with optical cantilever detection (FT-IR-PAS-OCD) prototype was assembled. In this article, the first evaluation and performance tests of the prototype are described. Selectivity, sensitivity, and the linearity of the signal response are evaluated. The linear response was studied for methane and carbon dioxide and confirmed in the whole analyzed concentration range from 500 to 3500 ppm and from 2500 to 17500 ppm, respectively. The calculated signal-to-noise ratio (SNR) and limit of detection were 2027 and 0.5 ppm for methane and 1362 and 4 ppm for carbon dioxide, with a measurement time of 100 seconds. Selectivity was studied with a multicomponent gas mixture of propene, methane, carbon dioxide, and methylmercaptane. The results indicate that a quantitative analysis of all components in the mixture is possible using the FT-IR-PAS-OCD.",
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Fourier transform infrared photoacoustic multicomponent gas spectroscopy with optical cantilever detection. / Hirschmann, Christian (Corresponding Author); Uotila, J.; Ojala, Satu; Tenhunen, Jussi; Keiski, R. L.

In: Applied Spectroscopy, Vol. 64, No. 3, 2010, p. 293-297.

Research output: Contribution to journalArticleScientificpeer-review

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T1 - Fourier transform infrared photoacoustic multicomponent gas spectroscopy with optical cantilever detection

AU - Hirschmann, Christian

AU - Uotila, J.

AU - Ojala, Satu

AU - Tenhunen, Jussi

AU - Keiski, R. L.

PY - 2010

Y1 - 2010

N2 - The sensitivity of photoacoustic spectroscopy was improved with the invention of optical cantilever detection (PAS-OCD). However, the ability of present PAS-OCD devices to carry out multicomponent detection is poor. To overcome this, a Fourier transform infrared photoacoustic spectrometer with optical cantilever detection (FT-IR-PAS-OCD) prototype was assembled. In this article, the first evaluation and performance tests of the prototype are described. Selectivity, sensitivity, and the linearity of the signal response are evaluated. The linear response was studied for methane and carbon dioxide and confirmed in the whole analyzed concentration range from 500 to 3500 ppm and from 2500 to 17500 ppm, respectively. The calculated signal-to-noise ratio (SNR) and limit of detection were 2027 and 0.5 ppm for methane and 1362 and 4 ppm for carbon dioxide, with a measurement time of 100 seconds. Selectivity was studied with a multicomponent gas mixture of propene, methane, carbon dioxide, and methylmercaptane. The results indicate that a quantitative analysis of all components in the mixture is possible using the FT-IR-PAS-OCD.

AB - The sensitivity of photoacoustic spectroscopy was improved with the invention of optical cantilever detection (PAS-OCD). However, the ability of present PAS-OCD devices to carry out multicomponent detection is poor. To overcome this, a Fourier transform infrared photoacoustic spectrometer with optical cantilever detection (FT-IR-PAS-OCD) prototype was assembled. In this article, the first evaluation and performance tests of the prototype are described. Selectivity, sensitivity, and the linearity of the signal response are evaluated. The linear response was studied for methane and carbon dioxide and confirmed in the whole analyzed concentration range from 500 to 3500 ppm and from 2500 to 17500 ppm, respectively. The calculated signal-to-noise ratio (SNR) and limit of detection were 2027 and 0.5 ppm for methane and 1362 and 4 ppm for carbon dioxide, with a measurement time of 100 seconds. Selectivity was studied with a multicomponent gas mixture of propene, methane, carbon dioxide, and methylmercaptane. The results indicate that a quantitative analysis of all components in the mixture is possible using the FT-IR-PAS-OCD.

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KW - FT-IR spectroscopy

KW - Cantilever microphone

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KW - Linearity

U2 - 10.1366/000370210790918490

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