Abstract
This study reports high numbers of exhaust emissions
particles during engine motoring. Such particles were
observed in the exhaust of two heavy duty vehicles with
no diesel particle filter (DPF), driven on speed ramp
tests and transient cycles. A significant fraction of
these particles was nonvolatile in nature. The
number-weighted size distribution peak was below 10 nm
when a thermodenuder was used to remove semivolatile
material, growing up to 40 nm after semivolatile species
condensation. These particles were found to contribute to
9-13% of total particle number emitted over a complete
driving cycle. Engine motoring particles originated from
lube oil and evidence suggests that these are of heavy
organic or organometallic material. Particles of similar
characteristics have been observed in the core particle
mode during normal fired engine operation. Their size and
chemical character has implications primarily on the
environmental toxicity of non-DPF diesel and,
secondarily, on the performance of catalytic devices and
DPFs. Lube oil formulation measures can be taken to
reduce the emission of such particles. (Graph Presented).
Original language | English |
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Pages (from-to) | 12504-12511 |
Journal | Environmental Science & Technology |
Volume | 50 |
Issue number | 22 |
DOIs | |
Publication status | Published - 2016 |
MoE publication type | A1 Journal article-refereed |
Keywords
- organometallics
- catalytic devices
- diesel particles
- engine operations
- environmental toxicity
- heavy duty vehicles
- heavy-duty diesel
- organometallic materials
- semi-volatile materials